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Reduction Precedes Cytidylyl Transfer without...
Journal article

Reduction Precedes Cytidylyl Transfer without Substrate Channeling in Distinct Active Sites of the Bifunctional CDP-Ribitol Synthase from Haemophilus influenzae †

Abstract

CDP-ribitol synthase is a bifunctional reductase and cytidylyltransferase that catalyzes the transformation of D-ribulose 5-phosphate, NADPH, and CTP to CDP-ribitol, a repeating unit present in the virulence-associated polysaccharide capsules of Haemophilus influenzae types a and b [Follens, A., et al. (1999) J. Bacteriol. 181, 2001]. In the work described here, we investigated the order of the reactions catalyzed by CDP-ribitol synthase and …

Authors

Zolli M; Kobric DJ; Brown ED

Journal

Biochemistry, Vol. 40, No. 16, pp. 5041–5048

Publisher

American Chemical Society (ACS)

Publication Date

April 1, 2001

DOI

10.1021/bi002745n

ISSN

0006-2960