Journal article
Synthesis of Ortho- and Meta-Re(I)-Metallocarboranes in Water
Abstract
A series of metallocarboranes of the types rac-[M(CO)3(eta(5)-7-R-7,8-C2B9H11)]-, rac-[M(CO)3(eta(5)-7-R-8-R'-7,8-C2B9H11)]-, and rac-[M(CO)3(eta(5)-7-R-7,9-C2B9H11)]- (M=Re) were prepared by reacting [NEt4]2[Re(CO)3Br3] or [Re(CO)3(OH2)3]Br with the corresponding carboranes in the presence of aqueous solutions of either alkali metal or tetraalkylammonium fluoride salts. Carborane derivatives that were investigated included those containing …
Authors
Sogbein OO; Green AEC; Schaffer P; Chankalal R; Lee E; Healy BD; Morel P; Valliant JF
Journal
Inorganic Chemistry, Vol. 44, No. 25, pp. 9574–9584
Publisher
American Chemical Society (ACS)
Publication Date
December 1, 2005
DOI
10.1021/ic0511221
ISSN
0020-1669