Synthesis of spindle-like amino-modified Zn/Fe bimetallic metal-organic frameworks as sorbents for dispersive solid-phase extraction and preconcentration of phytohormoes in vegetable samples

Amino-modified Zn/Fe bimetallic metal-organic frameworks (NH₂-Zn/Fe-MIL-88) were synthesized using a one-step solvothermal method with FeCl₃·6H₂O and Zn(NO₃)₂·6H₂O as metal salts and 2-aminoterephthalic acid as organic ligand. The morphology of NH₂-Zn/Fe-MIL-88 can be regulated from octahedral-like to spindle-like with changing molar ratios of metal salts. Using NH₂-Zn/Fe-MIL-88 as sorbent, a dispersive solid-phase extraction with putting …