Testing the functional tolerance of the Piers-Rubinsztajn reaction: a new strategy for functional silicones.
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The Piers-Rubinsztajn reaction, involving B(C(6)F(5))(3)-catalyzed siloxane formation from hydrosilanes + alkoxysilanes, is tolerant of a wide variety of functional groups, and provides a generic strategy for the preparation of structurally complex functional silicones.
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