Intercluster exchanges leading to hydride-centered bimetallic clusters: a multi-NMR, X-ray crystallographic, and DFT study Academic Article uri icon

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abstract

  • The tendency to reach dynamic equilibrium of intercluster reaction, Ag7(H) and Cu7(H), in solution is driven by a stepwise, one-metal exchange process, which has been illustrated by 2D EXSY NMR experiments.

authors

  • Zhong, Yu-Jie
  • Liao, Jian-Hong
  • Chiu, Tzu-Hao
  • Wu, Ying-Yann
  • Kahlal, Samia
  • Mcglinchey, Michael James
  • Saillard, Jean-Yves
  • Liu, CW

publication date

  • April 7, 2021