selected scholarly activity
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academic article
- Unravelling the Role of Uncommon Hydrogen Bonds in Cyclodextrin Ferrociphenol Supramolecular Complexes: A Computational Modelling and Experimental Study. International Journal of Molecular Sciences. 24:12288-12288. 2023
- Bioorganometallic chemistry – the early years. Journal of Organometallic Chemistry. 987-988:122623-122623. 2023
- Physicochemical Characterization of Ferrocifen Lipid Nanocapsules: Customized Drug Delivery Systems Guided by the Molecular Structure. Langmuir: the ACS journal of surfaces and colloids. 39:1885-1896. 2023
- The Effect of Benzannulation on the Structures, Reactivity and Molecular Dynamics of Indenes, Pentalenes, Azulenes and Related Molecules. Molecules. 27:3882-3882. 2022
- Diversity-oriented synthesis and bioactivity evaluation of N-substituted ferrocifen compounds as novel antiproliferative agents against TNBC cancer cells. European Journal of Medicinal Chemistry. 234:114202-114202. 2022
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Pt(
iv ) antitumor prodrugs: dogmas, paradigms, and realities. Dalton Transactions: an international journal of inorganic chemistry. 51:2121-2134. 2022 - Intercluster exchanges leading to hydride-centered bimetallic clusters: a multi-NMR, X-ray crystallographic, and DFT study. Dalton Transactions: an international journal of inorganic chemistry. 50:4727-4734. 2021
- Dynamics of a Molecular Rotor Exhibiting Local Directional Rotational Preference within Each Enantiomer. The Journal of Physical Chemistry A: Isolated Molecules, Clusters, Radicals, and Ions; Environmental Chemistry, Geochemistry, and Astrochemistry; Theory. 125:2061-2068. 2021
- Multifaceted chemical behaviour of metallocene (M = Fe, Os) quinone methides. Their contribution to biology. Coordination Chemistry Reviews. 430:213658-213658. 2021
- Ferrocenyl Migrations and Molecular Rearrangements: The Significance of Electronic Charge Delocalization. Inorganics. 8:68-68. 2020
- Diels-Alder Additions as Mechanistic Probes–Interception of Silyl-Isoindenes: Organometallic Derivatives of Polyphenylated Cycloheptatrienes and Related Seven-Membered Rings. Molecules. 25:4730-4730. 2020
- Enantioselective Synthesis of Planar Chiral Ferrocifens that Show Chiral Discrimination in Antiproliferative Activity on Breast Cancer Cells. ChemBioChem: a European journal of chemical biology. 21:2974-2981. 2020
- Palladium-Catalysed Coupling Reactions En Route to Molecular Machines: Sterically Hindered Indenyl and Ferrocenyl Anthracenes and Triptycenes, and Biindenyls. Molecules. 25:1950-1950. 2020
- Small Structural Differences between Two Ferrocenyl Diphenols Determine Large Discrepancies of Reactivity and Biological Effects. ChemMedChem: chemistry enabling drug discovery. 14:1717-1726. 2019
- Atypical Lone Pair–π Interaction with Quinone Methides in a Series of Imido‐Ferrociphenol Anticancer Drug Candidates. Angewandte Chemie International Edition. 58:8421-8425. 2019
- Atypical Lone Pair–π Interaction with Quinone Methides in a Series of Imido‐Ferrociphenol Anticancer Drug Candidates. Angewandte Chemie International Edition. 131:8509-8513. 2019
- A view on multi-action Pt(IV) antitumor prodrugs. Inorganica Chimica Acta. 492:32-47. 2019
- A mechanistic rationale for the outcome of Sonogashira cross-coupling of 9-bromoanthracene and ethynyltrimethylsilane: An unexpected product 4-(9-anthracenyl)-1,3-bis(trimethylsilyl)-3-en-1-yne. Journal of Organometallic Chemistry. 880:1-6. 2019
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Synthesis and characterization of cyclohexane-1R,2R-diamine-based Pt(
iv ) dicarboxylato anticancer prodrugs: their selective activity against human colon cancer cell lines. Dalton Transactions: an international journal of inorganic chemistry. 48:435-445. 2019 - Cover Feature: Syntheses, Structures and Dynamics of 9‐(Ferrocenylmethyl)anthracene and Related Molecular Gears: Phosphorus to the Rescue! (Eur. J. Org. Chem. 38/2018). European Journal of Organic Chemistry. 2018:5232-5232. 2018
- Syntheses, Structures and Dynamics of 9‐(Ferrocenylmethyl)anthracene and Related Molecular Gears: Phosphorus to the Rescue!. European Journal of Organic Chemistry. 2018:5260-5267. 2018
- Hexaethylbenzene: A Sterically Crowded Arene and Conformationally Versatile Ligand. ChemPlusChem. 83:480-499. 2018
- A new generation of ferrociphenols leads to a great diversity of reactive metabolites, and exhibits remarkable antiproliferative properties. Chemical Science. 9:70-78. 2018
- A New Series of Succinimido-ferrociphenols and Related Heterocyclic Species Induce Strong Antiproliferative Effects, Especially against Ovarian Cancer Cells Resistant to Cisplatin. Journal of Medicinal Chemistry. 60:8358-8368. 2017
- Protonation of Tetraphenyl- and 2,3,4-Triphenylcyclopentadienone - An NMR and X-ray Crystallographic Study. European Journal of Organic Chemistry. 2017:3249-3255. 2017
- Controlling the Reactivity of Ferrocenyl Carbocations: Routes to Enantiomerically Pure Chlorophosphites and Solid-State Characterization of a Benzopentalene Dimer. European Journal of Organic Chemistry. 2017:2848-2854. 2017
- Alkynyldicobalt Derivatives of Dibenzosuberenol and Dibenzocyclooctatrien‐5‐ol: Ring Conformations, Ease of Carbonyl Elimination and Relevance to Pauson–Khand Cyclization. European Journal of Inorganic Chemistry. 2017:2048-2057. 2017
- A Synthetic, X‐ray, NMR Spectroscopy and DFT Study of β‐Naphthil Dihydrazone, Di(β‐naphthyl)acetylene, Tetra(β‐naphthyl)cyclopentadienone, and Hexa(β‐naphthyl)‐benzene: C6(C10H7)6 Is a Disordered Molecular Propeller. ChemPlusChem. 82:433-441. 2017
- Side‐Chain Effects on the 1‐(Bis‐aryl‐methylidene)‐[3]ferrocenophane Skeleton: Antiproliferative Activity against TNBC Cancer Cells and Comparison with the Acyclic Ferrocifen Series. European Journal of Inorganic Chemistry. 2017:454-465. 2017
- Metal-stabilized carbocations derived from monoterpenes: dicobalt hexacarbonyl complexes of alkynyl-verbenols. Tetrahedron: the international journal for the rapid publication of full original research papers and critical reviews in organic chemistr. 72:4186-4193. 2016
- [Co2(CO)6(Alkynyl)] Complexes of Dibenzosuberyl and Dibenzosuberenyl Carbocations: Dibenzotropylium or Dibenzoheptafulvene?. ChemPlusChem. 81:292-306. 2016
- Organometallic derivatives of natural products: dicobalt hexacarbonyl complexes of geranyl-alkynes. New Journal of Chemistry: a journal for new directions in chemistry. 40:7881-7888. 2016
- Organometallic Antitumor Compounds: Ferrocifens as Precursors to Quinone Methides. Angewandte Chemie International Edition. 54:10230-10233. 2015
- Organometallic Antitumor Compounds: Ferrocifens as Precursors to Quinone Methides. Angewandte Chemie International Edition. 127:10368-10371. 2015
- C2-Symmetric 1,2-di(fluorenylidene)cyclobutanes: syntheses, structures, rearrangements and reactivity. Tetrahedron: the international journal for the rapid publication of full original research papers and critical reviews in organic chemistr. 71:5045-5054. 2015
- A Ferrocenyl Kaleidoscope: Slow Interconversion of Six Diastereo‐atropisomers of 2,6‐Di‐tert‐butyl‐9,10‐diferrocenyltriptycene. Chemistry: A European Journal. 21:4664-4670. 2015
- Symmetry Breaking in NMR Spectroscopy: The Elucidation of Hidden Molecular Rearrangement Processes. Symmetry. 6:622-654. 2014
- Atypical McMurry Cross-Coupling Reactions Leading to a New Series of Potent Antiproliferative Compounds Bearing the Key [Ferrocenyl-Ene-Phenol] Motif. Molecules. 19:10350-10369. 2014
- Direct measurement of the diamagnetic anisotropy of the ferrocenyl moiety: The origin of unusual 1H NMR shifts in ferrocenyl-triptycenes and barrelenes. Journal of Organometallic Chemistry. 751:809-814. 2014
- Organic and organometallic derivatives of pentaphenylbenzene, C6Ph5X: correlation of peripheral phenyl ring orientations with the steric bulk of “X”. Canadian Journal of Chemistry. 91:1098-1111. 2013
- Diels–Alder Reactions of 9-Ferrocenyl- and 9,10-Diferrocenylanthracene: Steric Control of 9,10- versus 1,4-Cycloaddition. Organometallics. 32:6118-6129. 2013
- ChemInform Abstract: Organic and Organometallic Derivatives of Propargylallene: Syntheses, Structures, Reactivity and Rearrangements. ChemInform. 44:no-no. 2013
- Organic and Organometallic Derivatives of Propargylallene: Syntheses, Structures, Reactivity and Rearrangements. European Journal of Organic Chemistry. 2013:4705-4728. 2013
- Synthesis of Isobavachalcone and Some Organometallic Derivatives. European Journal of Organic Chemistry. 2013:332-347. 2013
- High and Low Rotational Barriers in Metal Tricarbonyl Complexes of 2- and 3-Indenyl Anthracenes and Triptycenes: Rational Design of Molecular Brakes. Organometallics. 31:6183-6198. 2012
- Synthesis and Antiproliferative Effects of [3]Ferrocenophane Transposition Products and Pinacols Obtained from McMurry Cross-Coupling Reactions. Organometallics. 31:5856-5866. 2012
- From [10]Paracyclophane to Ferrocenophanones: The Search for Molecular Machines and Bio‐Organometallic Anticancer Drugs. Israel Journal of Chemistry. 52:30-40. 2012
- Different Rearrangement Behaviour of the Cation or Anion Derived from the Diels-Alder Adduct of 9-Ferrocenylanthracene and 1,4-Benzoquinone: Ring-Opening or Paddlewheel Formation. Chemistry: A European Journal. 17:14241-14247. 2011
- κ1- and κ2-Complexes of Fluorenylidene–Allenyl Phosphines and Phosphine Oxides with Palladium Chloride and Iron Carbonyl: Displacement of Trimethylsilyl by Diphenylphosphino via a Stabilized Carbanion. Organometallics. 30:3804-3817. 2011
- Stilbene analogues incorporating the Co(η4-C4Ph4)(η5-C5H4-) end group. Journal of Organometallic Chemistry. 696:1510-1527. 2011
- The preparation, spectroscopy, structure and electrochemistry of some [Co(η4-C4Ph4)(η5-C5H4R)] complexes. Journal of Organometallic Chemistry. 696:1496-1509. 2011
- Synthesis, characterization, structure, molecular modeling studies and biological activity of sterically crowded Pt(II) complexes containing bis(imidazole) ligands. Journal of Inorganic Biochemistry. 105:400-409. 2011
- Reciprocal polyhedra and the Euler relationship: cage hydrocarbons, CnHn and closo-boranes [BxHx]2−. Beilstein Journal of Organic Chemistry. 7:222-233. 2011
- Restricted Rotation in 9-Phenyl-anthracenes: A Prediction Fulfilled. Organic Letters. 13:256-259. 2011
- A new series of ferrocifen derivatives, bearing two aminoalkyl chains, with strong antiproliferative effects on breast cancer cells. New Journal of Chemistry: a journal for new directions in chemistry. 35:2212-2212. 2011
- Photoreactive gold(i) macrocycles with diphosphine and trans,trans-muconate ligands. Chemical Communications. 47:11633-11633. 2011
- π-Complexed polyfluoroarenes: a reactivity, bonding and spectroscopic study of (η6-C6F6)Cr(η6-C6H6) and related molecules. New Journal of Chemistry: a journal for new directions in chemistry. 35:2066-2066. 2011
- Molecular Dials: Hindered Rotations in Mono- and Diferrocenyl Anthracenes and Triptycenes. Journal of the American Chemical Society. 132:17617-17622. 2010
- Alkynyl-Dicobalt Hexacarbonyl Complexes of Menthyl Cations: Isolobal Substitution of [Co(CO)3]+by Fe(CO)3as a Structural Model. Organometallics. 29:4882-4892. 2010
- Severe Energy Costs of Double Steric Interactions: Towards a Molecular Clamp. European Journal of Organic Chemistry. 2010:5203-5216. 2010
- Different Reactivity Patterns of Trimethylsilyl- and Phenyl-Substituted Propargylallenes: Fe2(CO)9- and [Ag]+-Promoted Cyclizations. Organometallics. 29:676-686. 2010
- Organometallic SERMs (selective estrogen receptor modulators): Cobaltifens, the (cyclobutadiene)cobalt analogues of hydroxytamoxifen. Journal of Organometallic Chemistry. 695:595-608. 2010
- Syntheses, X-ray crystal structures and reactivity of fluorenylidene- and dibenzosuberenylidene-allenes: convenient precursors to dispirotetracenes, di-indenotetracenes and 2-phenyl-11bH-dibenz[cd,h]azulene. Organic and Biomolecular Chemistry. 8:3997-3997. 2010
- X-ray Crystallographic and NMR Spectroscopic Study of (η2-Alkene)(μ-alkyne)pentacarbonyldicobalt Complexes: Arrested Pauson−Khand Reaction Intermediates. Organometallics. 28:6308-6319. 2009
- A Synthetic and X‐ray Crystallographic Study of Zinc and Platinum Complexes of 4,5‐Diazafluoren‐9‐one (Dafone) and Dicobalt Hexacarbonyl Derivatives of 9‐Phenylethynyl‐4,5‐Diazafluoren‐9‐ol: Chelation versus Monocoordination. European Journal of Inorganic Chemistry. 2009:3250-3258. 2009
- A synthetic, structural and reactivity study of [(η4-C4R4)Co(η5-C5H4X)] complexes, R=Me or Et; X=CHO, CHCHFc, CHCH(η5-C5H4)Co(η4-C4Ph4), CHC(CN)2: Unexpected formation of [(η5-cyclopentadienyl)(η4-3,4,5,6-tetraethyl-α-pyrone)cobalt]. Journal of Organometallic Chemistry. 694:2536-2547. 2009
- ChemInform Abstract: From Allenes to Tetracenes: Syntheses, Structures, and Reactivity of the Intermediates. ChemInform. 40:no-no. 2009
- A Molecular Paddlewheel with a Sliding Organometallic Latch: Syntheses, X-Ray Crystal Structures and Dynamic Behaviour of [Cr(CO)3{η6-2-(9-triptycyl)indene}], and of [M(CO)3{η5-2-(9-triptycyl)indenyl}] (M=Mn, Re). Chemistry: A European Journal. 15:1836-1843. 2009
- From allenes to tetracenes: Syntheses, structures, and reactivity of the intermediates. Pure and Applied Chemistry. 81:1-17. 2009
- Role of aromatic substituents on the antiproliferative effects of diphenyl ferrocenyl butene compounds. Dalton Transactions: an international journal of inorganic chemistry. 0:4318-4318. 2009
- Synthesis, oxidation chemistry and cytotoxicity studies on ferrocene derivatives of diethylstilbestrol. Dalton Transactions: an international journal of inorganic chemistry. 0:10871-10871. 2009
- Unexpectedly different reactions of [(arene)Mn(CO)3]+ cations (arene = trindane, indane, tetralin, or dibenzosuberane) with potassium t-butoxide — C-H insertions, haptotropic shifts, dimerization, or elimination. Canadian Journal of Chemistry. 87:232-246. 2009
- Solvent-Mediated Generation of Cobalt-Cluster-Stabilised Propargyl Cations and Radicals: Allyl Migration versus Peroxide Formation. Chemistry: A European Journal. 14:10074-10084. 2008
- Unexpected Dimerization of a Bis(fluorenyl)-bis(trimethylsilyl)-diallene to a Dihydroquatercyclopentadiene, an Octacyclic C36 Fragment Corresponding to 60% of C60: Reaction of the Diallene with Fe2(CO)9. Organometallics. 27:5657-5664. 2008
- Syntheses, Structures, and Dimerizations of Ferrocenyl- and Fluorenylideneallenes: Push−Pull Multiple Bonds?. Organometallics. 27:4173-4182. 2008
- Twin Triptycyl Spinning Tops: A Simple Case of Molecular Gearing with Dynamic C2 Symmetry. European Journal of Organic Chemistry. 2008:3079-3084. 2008
- An investigation of the formation of 1,3,5-heterosubstituted benzene rings by cyclo-condensation of acetyl-substituted organometallic complexes. Journal of Organometallic Chemistry. 693:1957-1967. 2008
- Chromium, iron, ruthenium and gold complexes of 3,3-(biphenyl-2,2′-diyl)-1-diphenylphosphino-1-phenylallene: A versatile ligand. Journal of Organometallic Chemistry. 693:1759-1770. 2008
- Synthesis and Structure–Activity Relationships of the First Ferrocenyl-Aryl-Hydantoin Derivatives of the Nonsteroidal Antiandrogen Nilutamide. Journal of Medicinal Chemistry. 51:1791-1799. 2008
- Birch Reduction of Hexaphenyl- and Pentaphenylbenzene and an X-ray Crystallography and NMR Spectroscopy Study ofcis- andepi-1,2,3,4,5,6-Hexaphenylcyclohexane and of 2,3,5,6-Tetraphenyl-1,1′-bicyclohexylidene: Cannizzaro's Conundrum Revisited. Chemistry: A European Journal. 14:1552-1560. 2008
- Cannizzaro’s (C7H6)n conundrum resolved: [1.1.1]orthocyclophane was first made 150 years ago. Tetrahedron Letters: the international journal for the rapid publication of all preliminary communications in organic chemistry. 49:1527-1530. 2008
- Joining the rings: the preparation of 2- and 3-indenyl-triptycenes, and curious related processes. Organic and Biomolecular Chemistry. 5:1952-1960. 2007
- Cover Picture: From Allenes to Tetracenes: A Synthetic and Structural Study of Silyl‐ and Halo‐Allenes and Their Dimers (Eur. J. Org. Chem. 16/2007). European Journal of Organic Chemistry. 2007:2551-2551. 2007
- From Allenes to Tetracenes: A Synthetic and Structural Study of Silyl‐ and Halo‐Allenes and Their Dimers. European Journal of Organic Chemistry. 2007:2611-2622. 2007
- X-ray Crystal Structure of an Alkene–Pentacarbonyldicobalt–Alkyne Complex: Isolation of a Stable Magnus-Type Pauson–Khand Reaction Intermediate. Angewandte Chemie International Edition. 46:2907-2910. 2007
- X-ray Crystal Structure of an Alkene–Pentacarbonyldicobalt–Alkyne Complex: Isolation of a Stable Magnus-Type Pauson–Khand Reaction Intermediate. Angewandte Chemie International Edition. 119:2965-2968. 2007
- Sequential Formation of Yellow, Red, and Orange 1-Phenyl-3,3-Biphenylene-Allene Dimers Prior to Blue Tetracene Formation: Helicity Reversal intrans-3,4-Diphenyl-1,2-bis(fluorenylidene)cyclobutane. Chemistry: A European Journal. 12:3275-3286. 2006
- Aldol condensation reactions of [Co(η4-C4Ph4){η5-C5H4C(O)CH3}]. Journal of Organometallic Chemistry. 691:1183-1196. 2006
- Hexaethylbenzene complexes of ruthenium and manganese X-ray crystal structures and NMR spectra of [(HEB)2Ru2(µ-Cl)3][C5(CO2Me)5], [(HEB)Ru(H2O)3][BF4]2, (HEB)RuCl2[P(OMe)3], trans-RuCl2(PMe3)4, and (HEB)Mn(CO)2Br. Canadian Journal of Chemistry. 84:277-287. 2006
- High and low barriers to haptotropic shifts across polycyclic surfaces: the relevance of aromatic character during the migration process. Comptes Rendus de l'Academie des Sciences - Series IIc: Chemistry. 8:1497-1505. 2005
- Diastereoselective Addition of Allyl- and Crotylstannanes to Dicobalt-Complexed Acetylenic Aldehydes. Organometallics. 24:2617-2627. 2005
- Rac/meso Transformations of Disiloxane-bis(1-indenyl)-ansa-ferrocenes: An X-ray Crystallographic and NMR Study. Organometallics. 24:1533-1543. 2005
- A Convenient Synthetic Route to Benz[cd]azulenes: Versatile Ligands with the Potential To Bind Metals in an η5, η6, or η7Fashion. Chemistry: A European Journal. 10:5398-5405. 2004
- The First Organometallic Selective Estrogen Receptor Modulators (SERMs) and Their Relevance to Breast Cancer. Current Medicinal Chemistry. 11:2505-2517. 2004
- Toward an Organometallic Molecular Brake with a Metal Foot Pedal: Synthesis, Dynamic Behavior, and X-ray Crystal Structure of [(9-Indenyl)triptycene]chromium Tricarbonyl. Organometallics. 23:2884-2891. 2004
- An NMR study of the rotational barriers in cobalt-stabilized carbocations: X-ray crystal structures of (η4-C4Ph4)Co-(η5-C5H4R), where R is CH3CO, CHO, CH(tBu)OH. Journal of Organometallic Chemistry. 689:1657-1664. 2004
- Dimerization of 9-Phenylethynylfluorene to Di-indeno-naphthacene and Dispiro-[fluorene-dihydronaphthacene- fluorene]: An X-ray Crystallographic and NMR Study. Organic Letters. 6:787-790. 2004
- Synthesis, characterisation and redox behaviour of isocyanide incorporated, chalcogen stabilised mixed-metal clusters. Journal of Organometallic Chemistry. 689:122-133. 2004
- The alkyne-anion promoted ring-contraction of hexachlorotropone: synthesis and structure of [trimethylsilyl(pentachlorobenzoyl)ethyne]-hexacarbonyldicobalt. Journal of Organometallic Chemistry. 689:8-13. 2004
- Ferrocenyl-penta-(β-naphthyl)benzene Synthesis, structure, and dynamic behaviour. Canadian Journal of Chemistry. 81:1180-1186. 2003
- The Gomberg-type dimerization of bifluorenylidene radicals: an X-ray crystallographic investigation. Tetrahedron Letters: the international journal for the rapid publication of all preliminary communications in organic chemistry. 44:8057-8060. 2003
- Tamoxifen Derivatives for Delivery of the Antitumoral (DACH)Pt Group: Selective Synthesis by McMurry Coupling, and Biochemical Behaviour. ChemBioChem: a European journal of chemical biology. 4:754-761. 2003
- Versatile Bis‐Propargylic Reactivity of Acetylenedicarbonyl−Cobalt Complexes with Neutral C‐Nucleophiles: Direct Synthesis of a Furyl‐α‐pyrone. European Journal of Organic Chemistry. 2003:1652-1660. 2003
- Ring Opening of a Cobalt-Stabilized Bornyl Cation: Mechanistic Study of the Alkyne−Dicobalt/Carbynyl−Tricobalt Cluster Transformation. Organometallics. 22:1293-1301. 2003
- Spectroscopic and Computational Assessment of the Rotational Barrier of a Ferrocenyl-Stabilized Cyclopentadienyl Cation: Evidence for the First Hydroxyfulvalene Ligand. Organometallics. 22:663-669. 2003
- Conformations and Threshold Rotational Mechanisms of C5Ar5 and C5Ar4X Molecular Propellers: A Structure Correlation and Computational Study. Journal of Organic Chemistry. 67:7688-7698. 2002
- SiCl4ethanol as a trimerization agent for organometallics: convenient syntheses of the symmetrically substituted arenes 1,3,5-C6H3R3 where R = (C5H4)Mn(CO)3 and (C5H4)Fe(C5H5). Canadian Journal of Chemistry. 80:1546-1554. 2002
- Sterically hindered organometallics: multi-n-rotor (n=5, 6 and 7) molecular propellers and the search for correlated rotations. Coordination Chemistry Reviews. 233-234:75-105. 2002
- Rhodium complexes of 3,4-di(β-naphthyl)-2,5-diarylcyclopentadienone: indirect detection of slowed naphthyl rotation. Journal of Organometallic Chemistry. 656:243-257. 2002
- 2,5-Bis(diphenylmethylene)-3-cyclopentenone: a solvent-dependent cobalt cluster mediated propargyl radical coupling process. Tetrahedron Letters: the international journal for the rapid publication of all preliminary communications in organic chemistry. 43:4049-4053. 2002
- Synthesis, structure and mechanism of formation of chalcogen-stabilised mixed-metal clusters featuring acetylide bridging and acetylide coupling. Dalton Transactions: an international journal of inorganic chemistry. 4:619-629. 2002
- New insight into the dynamic behaviour of manganese ketene complexes: evidence for the scrambling of a carbene moiety over carbonyl ligands. Chemical Communications. 1:2636-2637. 2001
- Alkynylcyclohexanol Chairs and Twist-Boats: Co2(CO)6 as a Conformational Switch. Journal of Organic Chemistry. 66:8585-8591. 2001
- Ferrocenes derived from cyclopenta[l]phenanthrene: dibenzindene–metal complexes that resist haptotropic shifts. Journal of Organometallic Chemistry. 637-639:372-381. 2001
- Decomplexation of Cyclopentadienylmanganese Tricarbonyls under Very Mild Conditions: A Novel Route to Substituted Cyclopentadienes and Their Application in Organometallic Synthesis. Organometallics. 20:4554-4561. 2001
- Toward an Understanding of the Mechanism of Metal Exchange in (Propargyl Alcohol)Co2(CO)6 Clusters: Syntheses and Structures of [η5-C5Ph2R2−C⋮C−TMS)(Fe(CO)2(μ-H)]Co2(CO)6, R = Ph or Et. Organometallics. 20:4690-4694. 2001
- Unexpected Reaction of (trindane)Mn(CO)3+BF4- with Potassium tert-Butoxide: Three C−H Insertions and a Haptotropic Shift. Organometallics. 20:4147-4149. 2001
- η1-Indenyl derivatives of transition metal and main group elements: synthesis, characterization and molecular dynamics. Coordination Chemistry Reviews. 219-221:311-378. 2001
- 2000 Alcan Award Lecture Adventures in organometallic NMR: steric restraints, slowed rotations, and skeletal rearrangements. Canadian Journal of Chemistry. 79:1295-1309. 2001
- Dynamic equilibration of η1-carbene and η2-alkyne moieties within an alkynylcarbene dimanganese complex. Chemical Communications. 1:1690-1691. 2001
- Diels−Alder Adducts of 5-Alkynylcyclopentadienols with Tetracyanoethylene and Dimethyl Acetylenedicarboxylate: An X-ray Crystallographic Study of Unexpected Rearrangement Products. Journal of Organic Chemistry. 65:4861-4863. 2000
- Reactions of C6F5Li with Tetracyclone and 3-Ferrocenyl-2,4,5-triphenylcyclopentadienone: An 19F NMR and X-ray Crystallographic Study of Hindered Pentafluorophenyl Rotations. Journal of Organic Chemistry. 65:3652-3658. 2000
- Probing the Effect of Organic and Organometallic Functionalization on [1,5]-Silicon Shifts in Indenylsilanes. Organometallics. 19:590-601. 2000
- Rhodium Acetylacetonate and Iron Tricarbonyl Complexes of Tetracyclone and 3-Ferrocenyl-2,4,5-triphenylcyclopentadienone: An X-ray Crystallographic and NMR Study. Organometallics. 19:184-191. 2000
- The molecular dynamics and reactivity of tris(inden-1-yl)silane: an NMR spectroscopic and X-ray crystallographic study †. Journal of the Chemical Society, Perkin Transactions 2. 4:611-618. 2000
- Metal Cluster Stabilized Fluorenyl, Indenyl, and Cyclopentadienyl Antiaromatic Cations: An NMR and X-ray Crystallographic Study. Organometallics. 18:3372-3382. 1999
- Reactions of Dimethoxycarbene with Cyclic Perchlorinated Olefins and Ketones. Journal of Organic Chemistry. 64:4344-4352. 1999
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Diels-Alder Reactions of 3-Ferrocenyl-2,4,5-triphenylcyclopentadienone: Syntheses and Structures of the Sterically Crowded Systems C
6 Ph5 Fc, C7 Ph6 FcH, and [C7 Ph6 FcH][SbCl6 ]. Organometallics. 18:115-122. 1999 - Diels−Alder Reactions of 3-Ferrocenyl-2,4,5-triphenylcyclopentadienone: Syntheses and Structures of the Sterically Crowded Systems C6Ph5Fc, C7Ph6FcH, and [C7Ph6FcH][SbCl6]. Organometallics. 18:115-122. 1999
- The molecular dynamics and cycloaddition chemistry of tris(1-indenyl)allylsilane Part 1Generation of the first crystallographically characterized tris(benzonorbornyl)silane. New Journal of Chemistry: a journal for new directions in chemistry. 23:317-321. 1999
- Metal-Mediated Allyl Transfers in (Alkynylallylsilane)Co2(CO)6 Complexes: A Synthetic and Structural Study. Organometallics. 17:4992-4996. 1998
- A synthetic and X-ray crystallographic study of the indenyl-phosphine complexes 1,3-(Ph2PX)2(C9H6), (X=O, S) and (η5-C9H5(Ph2PS)2)[Mn(CO)3]: versatile ligands for the preparation of heteropolymetallic complexes. Journal of Organometallic Chemistry. 564:101-108. 1998
- The Structure of a Seven-Bladed Propeller: C7Ph7+ is Not Planar. Chemistry: A European Journal. 4:1201-1205. 1998
- Diels−Alder Dimerization of Cyclopenta[l]phenanthrene (Dibenz[e,g]indene) with Isodibenzindene: A Computational, NMR Spectroscopic, and X-ray Crystallographic Study. Journal of Organic Chemistry. 63:3735-3740. 1998
- Can metal clusters assist silicon migrations? An NMR spectroscopic and X-ray crystallographic study. Inorganic Chemistry Communications. 1:105-108. 1998
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The fluxional character of (η5-C
5 H5 )Fe(CO)2 (η 1-C9 H7 ): Evidence for the [4 + 2] cycloaddition of a metal-substituted isoindene with tetracyanoethylene. Organometallics. 16:5563-5568. 1997 - A synthetic and structural study on metal cluster complexes of allyl—alkynyl—silanes: Does protonation lead to metal-stabilized silyl cations?. Journal of Organometallic Chemistry. 547:217-226. 1997
- The Fluxional Character of (η5-C5H5)Fe(CO)2(η1-C9H7): Evidence for the [4 + 2] Cycloaddition of a Metal-Substituted Isoindene with Tetracyanoethylene. Organometallics. 16:5563-5568. 1997
- Oligo(alkynylsilanes): Templates for Organometallic Polymers. Organometallics. 16:5048-5057. 1997
- Using Hydrosilylation To Assemble Organometallic Polymers Containing Combinations of Silicon-Based Functional Groups. Organometallics. 16:5042-5047. 1997
-
Trindane-ruthenium sandwich complexes: An NMR and X-ray crystallographic study of [(trindane)RuCl
2 ]2 , (trindane)RuCl2 [P(OMe)3 ], and [(trindane)2 Ru][BF4 ]2 . Organometallics. 16:4355-4361. 1997 - Trindane−Ruthenium Sandwich Complexes: An NMR and X-ray Crystallographic Study of [(trindane)RuCl2]2, (trindane)RuCl2[P(OMe)3], and [(trindane)2Ru][BF4]2. Organometallics. 16:4355-4361. 1997
- Metal Complexes of Trindane: Possible Precursors of Sumanene. Organometallics. 16:3628-3634. 1997
- Niobium and Tantalum Diphosphanato Complexes: Synthesis, Structure, and NMR Studies of Cp2MH[(PR)2] (R = Ph, Cy, H). Organometallics. 16:3504-3510. 1997
- Ferrole-estradiol complex as a test for receptor dimerization. Journal of Organometallic Chemistry. 533:97-102. 1997
- Haptotropic Shifts in (C5H5)Fe and Mn(CO)3 Complexes of 4H-Cyclopenta[def]phenanthrene (cppH): X-ray Crystal Structure and NMR Fluxionality of (η1-cpp)Mn(CO)3(PEt3)2. Organometallics. 16:1308-1315. 1997
- Multidimensional NMR Study of Tris(indenyl)methylsilane: Molecular Dynamics Mapped onto a Hypercube. Organometallics. 15:5645-5652. 1996
- The metal-mediated conversion of octachlorocycloheptatriene into dodecachloroheptafulvalene: a synthetic, structural, and EHMO study. Canadian Journal of Chemistry. 74:2258-2267. 1996
- Do aromatic transition states lower barriers to silatropic shifts? A synthetic, NMR spectroscopic, and computational study. Inorganica Chimica Acta. 251:355-364. 1996
- Do aromatic transition states lower barriers to silatropic shifts? A synthetic, NMR spectroscopic, and computational study. Inorganica Chimica Acta. 251:355-364. 1996
- Delocalized bonding in tetrahedral organo-transition metal clusters: an EHMO study of metal vertex rotations in Co2Fe(CO)9S, CpMoCo2(CO)8CR, and in Cp2Mo2(CO)4(RC≡CR). Canadian Journal of Chemistry. 74:1021-1031. 1996
- Covalent and Selective Labeling of Proteins with Heavy Metals. Synthesis, X-ray Structure, and Reactivity Studies of N-Succinimidyl and N-Sulfosuccinimidyl Ester Organotungsten Complexes. Organometallics. 15:142-151. 1996
- Organometallics as Potential Protein Labels: Pyrylium and Pyridinium Salts Bearing (C6H5)Cr(CO)3, (C5H4)Mn(CO)3, and Ferrocenyl Substituents. Organometallics. 14:5273-5280. 1995
- Structure of 2-Methyl-1-(phenylethynyl)cyclopentanol and of Its Co2(CO)6 and (C5H5)2Mo2(CO)4 Cluster Complexes Co2(CO)6 as a Conformational Switch. Organometallics. 14:4676-4684. 1995
- Cluster-stabilized cations: synthesis, structures, molecular dynamics and reactivity. Coordination Chemistry Reviews. 143:331-381. 1995
- The barriers to trimethylsilyl migrations in indenes and benzindenes: Silatropic shifts via aromatic transition states. Polyhedron. 14:2787-2796. 1995
- Molecular Dynamics of dl- and meso-Bis(indenyl)dimethylsilane: Reexamination of the Mechanism of Interconversion by using Single Selective Inversion NMR. Organometallics. 14:3798-3801. 1995
- Rhenium Carbonyl Complexes of .beta.-Estradiol Derivatives with High Affinity for the Estradiol Receptor: An Approach to Selective Organometallic Radiopharmaceuticals. Journal of the American Chemical Society. 117:8372-8380. 1995
- A Synthetic and X-Ray Crystallographic Study of Cobalt and Molybdenum Cluster Complexes of the 2-Fenchyl Cation: Metal-Mediated Wagner-Meerwein Rearrangements. Journal of the American Chemical Society. 117:6907-6913. 1995
- Organic and inorganic templates bearing CCo3(CO)9 cluster fragments: X-ray crystal structures of C(CH2OCOCCl3)4 and of CH3C(O)CHC(OH)MLn where MLn = CCo3(CO)9 or (C6H5)Cr(CO)3. Canadian Journal of Chemistry. 73:1196-1205. 1995
- Chromium and Molybdenum Carbonyl Complexes of C7Ph7H and C7Ph5Me2H and of C7Ph7H(CO), the Diels-Alder Adduct of Tetracyclone and Triphenylcyclopropene: Variable-Temperature NMR and X-ray Crystallographic Study. Organometallics. 14:1139-1151. 1995
- SURPRISINGLY FACILE DECOMPOSITION OF THE DICATION [(C(5)ME(5))IR(MEO-C6H4-CH2CO2NCOCH2CH2CO)](2+) - A METAL-MEDIATED HUNSDIECKER REACTION OF A SUCCINIMIDYL ESTER. Journal of Organometallic Chemistry. 485:79-84. 1995
- Surprisingly facile decomposition of the dication : a metal-mediated Hunsdiecker reaction of a succinimidyl ester?. Journal of Organometallic Chemistry. 485:79-84. 1995
- NMR Study of the Dynamic Behavior of [(2-propynylbornyl)Mo2(CO)4Cp2]+ BF4-: Nonfluxional Molybdenum-Cobalt Clusters as the Key to Understanding the Mechanism of the Formation of Metal-Stabilized Cations. Organometallics. 13:5149-5156. 1994
- A Comparative Study of the Structures and Fluxionality of the Carbenium Ion Complexes [FvMo2(CO)4(.mu.-.eta.2,.eta.3-RC.tplbond.CCR'2)]+BF4- (R = H, Me; R' = H, Me, Ph; Fv = Fulvalene): X-ray Crystal Structure of [FvMo2(CO)4(.mu.-.eta.2,.eta.3-HC.tplbond.CCMe2)]+BF4-. Organometallics. 13:4426-4430. 1994
- Toward Metal-Stabilized Silylium Cations: An EHMO Study of [(HC.tplbond.C-SiH2)Co2(CO)6]+ and X-ray Crystal Structures of (Me3SiC.tplbond.CSiPh2H)Mo2(CO)4Cp2 and [(Me3SiC.tplbond.CSiMe2)Co2(CO)6]2O. Organometallics. 13:4328-4335. 1994
- Mono-, di- and tri-metallic complexes of trimethylenemethane: an EHMO study of the TMM rotational barrier. Journal of Organometallic Chemistry. 478:179-188. 1994
- The rearrangement pathway in [Cp2Mo2(CO)4(RCCCR2)]+ cations: An extended Hückel molecular orbital and Bürgi-Dunitz trajectory study. Journal of Organometallic Chemistry. 478:189-196. 1994
- Synthesis and X-ray Crystal Structure of (1,2,4,5-Tetramethylenebenzene)Fe3(CO)9: A Metal-Stabilized Disjoint Hydrocarbon. Journal of the American Chemical Society. 116:6427-6428. 1994
- Bis(cyclopentadienyl)zirconium and -hafnium Macrocycles Containing Siloxane Bridges: Synthesis of [(.eta.5-C5H5)2M{.mu.-OSi(C6H5)2O}]2 (M = Zr, Hf) and Crystal Structure and EHMO Study for M = Zr. Inorganic Chemistry: including bioinorganic chemistry. 33:1292-1296. 1994
- Ionization of (.eta.6-diphenylmethane)(.eta.5-cyclopentadienyl)iron cations in H2O-Me2SO and methanol-Me2SO mixtures: a kinetic, NMR, and EHMO study. Organometallics. 13:690-697. 1994
- Multiple fluxional processes in chiral (pentaphenylcyclopentadienyl)iron complexes: X-ray crystal structure of (C5Ph5)Fe(CO)(PMe3)(HC:O) and the barriers to aryl, phosphine, and tripodal rotation in (C5Ph5)Fe(CO)(PMe2Ph)C(O)Et. Organometallics. 13:682-689. 1994
- Metal cluster stabilized 2-bornyl cations: a synthetic, x-ray crystallographic, and EHMO study. Organometallics. 12:4917-4925. 1993
- Modification of estradiol at the 17-position. Effect of changing the OH group for a transition-metal carbonyl cluster on the estradiol receptor recognition. Organometallics. 12:4545-4552. 1993
- Inner-shell spectroscopies of solid and gaseous alkylidyne tricobalt nonacarbonyl complexes. Journal of the Chemical Society - Faraday Transactions. 89:3331-3345. 1993
- Facile haptotropic shifts in organometallic complexes of 4H-cyclopenta[def]phenanthrene via naphthalene-type transition states: synthetic, x-ray crystallographic, NMR spectroscopic, and EHMO studies. Journal of the American Chemical Society. 115:7275-7284. 1993
- Protonation of chromium tricarbonyl complexes of triphenylsilanol and triphenylcarbinol: synthetic, x-ray crystallographic, and NMR study of (Ph3SiOH)[Cr(CO)3]n (n = 1-3) and of (Ph3COH)Cr(CO)3. Organometallics. 12:2462-2471. 1993
- Molecular recognition using bioorganometallic probes: NMR, x-ray crystallographic, and molecular modeling study of the conformations of chromium tricarbonyl derivatives of hexestrol and their relevance to estradiol-receptor binding. Organometallics. 11:4061-4068. 1992
- Carbon-13 NMR spectroscopic and EHMO study of slowed tripodal rotation in [(benzyl)Cr(CO)3]+ and (fulvene)Cr(CO)3 systems: metal-stabilized nonplanar cations. Organometallics. 11:3281-3286. 1992
- An X-ray crystallographic and high field NMR study of [7-dehydrocholesteryl acetate]Fe(CO)3: Synthesis of a B-ring cyclohexadienyl cationic complex. Journal of Organometallic Chemistry. 435:357-376. 1992
- A variable-temperature 13C NMR study of (η5-C5H5)2Mo2(CO)4 complexes of chiral alkynes derived from a terpene or a hormonal steroid: interconversion of diastereomers via exchange of terminal and semi-bridging carbonyls. Canadian Journal of Chemistry. 70:1743-1749. 1992
- Synthetic, structural, and reactivity studies of dirhenium carbonyl complexes of 17.alpha.-ethynylestradiol and phenylacetylene: variable-temperature carbon-13 NMR spectra and x-ray crystal structure of (.mu.-H)(.mu.-C.tplbond.C-R)Re2(CO)7(MeCN). Organometallics. 11:1201-1209. 1992
- Slowed Tripodal Rotation in Arene-Chromium Complexes: Steric and Electronic Barriers. Advances in Organometallic Chemistry. 34:285-325. 1992
- Variable-temperature 1- and 2-dimensional carbon-13 NMR studies on CH3CCo3(CO)8P(c-C6H11)3: the mechanism of carbonyl migration. Organometallics. 11:477-481. 1992
- High-field NMR study of vertex rotation in (C5HnMe5-n)MCo2(CO)8CR clusters (M = molybdenum, tungsten): x-ray crystal structure of (C5Me5)MoCo2(CO)8CCO2-iso-Pr. Organometallics. 10:2362-2370. 1991
- X-ray crystallographic and variable-temperature high-field carbon-13 NMR studies of R-CCo3(CO)9 and R-CCo3 (CO)6 (tripod) clusters [R = Ch3, (4-CH3OC6H4)2CH, (2-CIC6H4) (4-CIC6H4)CH; tripod = 1,1,1-tris(diphenylphosphino)methane]enantiomerization of a chiral cluster via the inversion of a molecular propeller. Organometallics. 10:1383-1390. 1991
- Gas-phase molecular structure of (.eta.5-cyclopentadienyl)tris(tetrahydroborato)zirconium: electron-diffraction and EHMO study. Inorganic Chemistry: including bioinorganic chemistry. 30:1371-1376. 1991
- An x-ray crystallographic and high-field NMR study of chromium complexes [(C6Et6)Cr(CO)2NO]+BF4- and [(C6Et6)Cr(CO)(CS)NO]+BF4-: steric inhibition of tripodal rotation. Journal of the American Chemical Society. 113:1177-1185. 1991
- Diastereoselective ligand and vertex substitutions in bimetallic bridged alkyne clusters: x-ray crystal structure of .mu.2-(endo-2-propynylborneol)hexacarbonyldicobalt. Organometallics. 9:2972-2984. 1990
- Structures of zearalenone and zearalanone in solution: A high-field NMR and molecular modelling study. Magnetic Resonance in Chemistry. 28:835-845. 1990
- The reaction of [(η5-cyclohexadienyl)Fe(CO)3]+BF4− with 2-methyl-2-nitrosopropane: an unexpected oscillating reaction. Journal of Organometallic Chemistry. 396:65-72. 1990
- The fluxional behaviour of hexaphenylbenzene chromium tricarbonyl: A variable-temperature 13C NMR spectroscopic study. Journal of Organometallic Chemistry. 395:177-185. 1990
- An NMR spectroscopic and EHMO investigation of cationic mixed metal clusters: X-ray crystal structure of (1,7,7-trimethyl-μ2-2-propynylnorbornene)-bis(cyclopentadienyl)tetracarbonyldimolybdenum. Journal of Organometallic Chemistry. 394:145-166. 1990
- Protonation of tricarbonyl(hexaethylbenzene)chromium and -tungsten: a carbon-13 NMR and extended Hueckel MO investigation. Organometallics. 9:1089-1093. 1990
- ChemInform Abstract: Unequivocal Proof of Slowed Chromium Tricarbonyl Rotation in a Sterically Crowded Arene Complex: An X-Ray Crystallographic and Variable-Temperature High-Field NMR Study of (C6Et5COCH3)Cr(CO)3.. ChemInform. 21:no-no. 1990
- Syntheses and NMR spectra of Co3(CO)9[.mu.3-CCHAr2] clusters derived from DDT and related molecules: x-ray crystal structures of [[bis(4-chlorophenyl)methyl]carbynyl]tricobalt nonacarbonyl and of its bis(4-chloronaphthyl) analog. Organometallics. 9:20-26. 1990
- Unequivocal proof of slowed chromium tricarbonyl rotation in a sterically crowded arene complex: an x-ray crystallographic and variable-temperature high-field NMR study of (C6Et5COCH3)Cr(CO)3. Journal of the American Chemical Society. 112:27-32. 1990
- Structural features of (C5H5)2Mo2S6 clusters: an EHMO study. Canadian Journal of Chemistry. 67:1931-1935. 1989
- The reactions of nitrosoarenes with cationic cyclohexadienyl complexes of iron tricarbonyl: an ESR study. Canadian Journal of Chemistry. 67:1868-1877. 1989
- ChemInform Abstract: (Cyclopentadienyl)ruthenium Complexes of 3-Methoxyestrone: A High-Field NMR and X-Ray Crystallographic Study.. ChemInform. 20:no-no. 1989
- ChemInform Abstract: Heterometallic Alkylidyne Clusters: Natural Products as Sources of Chirality.. ChemInform. 20:no-no. 1989
- (Cyclopentadienyl)ruthenium complexes of 3-methoxyestrone. A high-field NMR and x-ray crystallographic study. Organometallics. 8:960-967. 1989
- ChemInform Abstract: Synthetic and High Field NMR Studies of Chiral Clusters.. ChemInform. 20:no-no. 1989
- Heterometallic alkylidyne clusters: natural products as sources of chirality. Organometallics. 8:155-161. 1989
- Fe(CO)3 and Rh(acac) complexes of ergosteryl and 7-dehydrocholesteryl acetates: A high field nuclear magnetic resonance study. Canadian Journal of Chemistry. 66:3003-3011. 1988
- Chromium tricarbonyl complexes of methyl O-methylpodocarpate: differentiation of diastereomers by high field NMR spectroscopy. Journal of Organometallic Chemistry. 354:325-340. 1988
- HIGH-FIELD NMR-STUDIES OF FLUXIONAL METAL-CLUSTERS - THE ORIENTATION OF THE CAPPING ARYL GROUP IN CARBYNYL-TRIMETALLIC CLUSTERS. New Journal of Chemistry: a journal for new directions in chemistry. 12:419-426. 1988
- Mixed metal acylium clusters: A chemical and spectroscopic study. Journal of Organometallic Chemistry. 345:371-382. 1988
- Mixed metal clusters containing carbyne or ketenylidene bridges: High field NMR spectroscopy as a probe for structure and mechanism. Polyhedron. 7:807-825. 1988
- Synthetic and high field NMR studies of chiral clusters. Polyhedron. 7:2297-2305. 1988
- Tricarbonylchromium(0) complexes of 1,3,5-triphenylbenzene: an X-ray crystallographic and high field NMR spectroscopic study. Journal of Organometallic Chemistry. 335:213-227. 1987
- Protonation of bis(ethylene)(.eta.5-indenyl)rhodium and (cyclooctatetraene)(.eta.5-indenyl)rhodium: a 500-MHz NMR study. Organometallics. 6:2201-2207. 1987
- ChemInform Abstract: Bonding Capabilities of Nickel Cluster Ions: Synthetic Chemistry in a Molecular Beam.. ChemInform. 18:no-no. 1987
- Mechanism of the decarbonylation of RC(O)CCo3(CO)9 to RCCo3(CO)9: migration of the ketonic carbonyl. Organometallics. 6:1181-1184. 1987
- Bonding capabilities of nickel cluster ions: synthetic chemistry in a molecular beam. Journal of the American Chemical Society. 109:1733-1738. 1987
- Ph2AsCH2CH2PPh2 (arphos) and Ph2PCH2CH2PPh2 (diphos) complexes of Co2(CO)6MCCO2CHMe2 [M = Co(CO)3, (C5Me5)Mo(CO)2]: x-ray crystal structure and NMR fluxionality. Organometallics. 6:439-447. 1987
- ChemInform Abstract: Organometallic Derivatives of Hormonal Steroids: 500-MHz One- and Two- Dimensional NMR Spectra of 17α-Propynylestra-1,3,5(10)-triene-3,17β- diol and Its Co2(CO)6 and (C5H5)2Mo2(CO)4 Complexes.. ChemInform. 18:no-no. 1987
- Carbon-13 NMR and EHMO studies on Seyferth's [Co3(CO)9CCO]+ cluster: to bend or not to bend. Organometallics. 5:2345-2350. 1986
- X-ray crystal structure and molecular dynamics of (indenyl)bis(ethylene)rhodium(I): 500-MHz NMR spectra and EHMO calculations. Organometallics. 5:1656-1663. 1986
- Organometallic derivatives of hormonal steroids: 500-MHz one- and two-dimensional NMR spectra of 17.alpha.-propynylestra-1,3,5(10)-triene-3,17.beta.-diol and its Co2(CO)6 and (C5H5)2Mo2(CO)4 complexes. Journal of Organic Chemistry. 51:2328-2332. 1986
- The hydrolysis of (π-C6H6)Cr(π-C6F5CO2C2H5): an unexpected decarboxylation. Canadian Journal of Chemistry. 64:1170-1172. 1986
- CpMoCo2(CO)8CCO+: Synthesis and characterization of a mixed metal acylium cation. Journal of Organometallic Chemistry. 303:361-366. 1986
- Diamagnetic anisotropy of organometallic moieties: .chi. values for M(CO)3 (M = Cr, Mo, W) and for ferrocene. Organometallics. 5:104-109. 1986
- Electron counting in square-pyramidal organo-transition-metal carbides: can a carbon atom be a vertex of a closo octahedral M5C cluster. Organometallics. 5:139-145. 1986
- Chromium tricarbonyl complexes of estradiol derivatives: differentiation of .alpha.- and .beta.-diastereoisomers using 1- and 2-dimensional NMR spectroscopy at 500 MHz. Organometallics. 4:2143-2150. 1985
- Fluxionality of M2C2 tetrahedral clusters containing cyclopentadienyldicarbonylmetal vertices: Unexpectedly different behaviour of molybdenum and tungsten analogues. Journal of Organometallic Chemistry. 296:383-391. 1985
- A rationalized synthesis and x-ray crystal structure of Cp3Co2MoFe(CO)5CCO2-i-Pr: a heterometallic M4C closo cluster. Organometallics. 4:2046-2053. 1985
- ChemInform Abstract: MOLECULAR ORBITAL STUDY OF HETEROMETALLIC M3C2 ORGANO-TRANSITION-METAL CLUSTERS: ORIENTATION OF THE ALKYNE MOIETY. ChemInform. 16:no-no. 1985
- ChemInform Abstract: MULTINUCLEAR MAGNETIC RESONANCE STUDY OF TRI(CYCLOPENTADIENYL)SCANDIUM: A FLUXIONAL DIMER WITH BRIDGING CYCLOPENTADIENYL GROUPS. ChemInform. 16:no-no. 1985
- Syntheses, crystal structures and DNMR studies on the mixed clusters CpNiFe(CO)3(RC.tplbond.CR')M [M = CpNi, Co(CO)3, Mo(CO)2Cp]: some comments on the acetylene rotation process. Organometallics. 4:1123-1130. 1985
- ChemInform Abstract: NMR STUDIES OF NICKEL HYDRIDES: THE INTRAMOLECULAR REARRANGEMENT OF THE HYDRIDOTRIS(TRI-P-TOLYL PHOSPHITE)NICKEL(II) ION. ChemInform. 16:no-no. 1985
- ChemInform Abstract: RING CURRENTS, NMR CHEMICAL SHIFTS, AND HOMOAROMATICITY: THE HOMOTROPYLIUM ION REVISITED. ChemInform. 16:no-no. 1985
- ChemInform Abstract: TETRA(TERT-BUTYL)ZIRCONIUM: SYNTHESIS, CHARACTERIZATION AND REACTION WITH CARBON DIOXIDE. ChemInform. 16:no-no. 1985
- ChemInform Abstract: THE CHLOROSILANE-MEDIATED DIMERIZATION OF PENTANE-2,4-DIONES: A DIRECT ROUTE TO PYRANS. ChemInform. 16:no-no. 1985
- Molecular orbital study of heterometallic M3C2 organo-transition-metal clusters: orientation of the alkyne moiety. Inorganic Chemistry: including bioinorganic chemistry. 24:218-224. 1985
- Multinuclear magnetic resonance study of tri(cyclopentadienyl)scandium: a fluxional dimer with bridging cyclopentadienyl groups. Inorganic Chemistry: including bioinorganic chemistry. 24:93-95. 1985
- Titanium NMR spectroscopy: A comment on some recent assignments. Polyhedron. 4:1147-1148. 1985
- NMR studies of nickel hydrides: the intramolecular rearrangement of the hydridotris(tri-p-tolyl phosphite)nickel(II) ion. Journal of the American Chemical Society. 106:8110-8116. 1984
- Ring currents, NMR chemical shifts, and homoaromaticity: the homotropylium ion revisited. Journal of the American Chemical Society. 106:5974-5978. 1984
- Tetra(tert-butyl)zirconium: synthesis, characterisation and reaction with carbon dioxide. Inorganica Chimica Acta. 89:133-138. 1984
- The chlorosilane-mediated dimerization of pentane-2,4-diones: a direct route to pyrans. Inorganica Chimica Acta. 89:139-142. 1984
- ChemInform Abstract: BONDING IN TRANSITION-METAL TETRAHYDROBORATES: A MULTINUCLEAR MAGNETIC RESONANCE STUDY OF (C5H5)2SC(BH4) AND SC(BH4)3 AND SOME COMMENTS ON THE ISOLOBALITY OF BH4-, HALIDE, AND η5-C5H5- GROUPS. ChemInform. 15:no-no. 1984
- Bonding in transition-metal tetrahydroborates: a multinuclear magnetic resonance study of (C5H5)2Sc(BH4) and Sc(BH4)3 and some comments on the isolobality of BH4-, halide, and .eta.5-C5H5- groups. Inorganic Chemistry: including bioinorganic chemistry. 23:1072-1078. 1984
- [η5-1,2,3,4,5-pentakis(carbomethoxy)cyclopentadienyl]tricarbonylmanganese(I): Synthesis, spectroscopy and reactivity. Journal of Organometallic Chemistry. 265:283-290. 1984
- ChemInform Abstract: ROTATIONAL BARRIERS IN DIPHENYLMETHYL ANIONS STABILIZED BY TRIMETHYLSILYL AND TRICARBONYLCHROMIUM(0) MOIETIES. ChemInform. 15:no-no. 1984
- ChemInform Abstract: DICYCLOPENTADIENYLNICKEL: A PROBLEMATICAL REAGENT IN CLUSTER SYNTHESIS. ChemInform. 15:no-no. 1984
- Solid state 13C and high resolution 1H and 13C n.m.r. spectra of dicarbony(hexaethylbenzene)thiocarbonylchromium(0): a reaffirmation of slowed tripodal rotation. Chemical Communications. 0:789-789. 1984
- Rotational barriers in diphenylmethyl anions stabilized by trimethylsilyl and tricarbonylchromium(0) moieties. Journal of the American Chemical Society. 105:6426-6429. 1983
- Dicyclopentadienylnickel: A problematical reagent in cluster synthesis. Journal of Organometallic Chemistry. 253:117-121. 1983
- Organo-transition metal clusters: rational approaches to synthesis, structure, fluxionality, and reactivity. Canadian Journal of Chemistry. 61:1319-1331. 1983
- ChemInform Abstract: ORGANOMETALLIC ELECTRON RESERVOIRS. 7. ONE-STEP MULTIPLE FORMATION OF CARBON-CARBON BONDS IN CPFE+(ARENE) SANDWICHES AND UNUSUAL C6ET6 GEOMETRY IN THE X-RAY CRYSTAL STRUCTURE OF CPFE+(η6-C6ET6) PF6-. ChemInform. 14:no-no. 1983
- Reaction of [η5-C5H5)2ZrH(μ-H)]2 with diphenylacetylene: mechanistic and theoretical considerations. Journal of Organometallic Chemistry. 246:257-268. 1983
- Asymmetrical sandwich compounds. The preparation and characterization of (.eta.6-benzene)[.eta.6-1,2,3,4,5-pentafluoro-6-(diphenylphosphino)benzene]chromium(0) and its reaction with dicarbonyldichlororhodium. Organometallics. 2:96-100. 1983
- Infrared and Raman spectra of C6H6C6F6. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 39:863-866. 1983
- Stopping a chromium carousel: X-ray crystallographic and variable-temperature13C n. m. r. studies on dicarbonyl(hexaethylbenzene)-thiocarbonylchromium(0) and related complexes. Chemical Communications. 0:634-636. 1983
- Organometallic electron reservoirs. 7. One-step multiple formation of carbon-carbon bonds in CpFe+(arene) sandwiches and unusual C6Et6 geometry in the x-ray crystal structure of CpFe+(.eta.6-C6Et6) PF6-. Journal of the American Chemical Society. 104:7549-7555. 1982
- Titanium-47 and -49 nuclear magnetic resonance spectroscopy: Chemical applications. Journal of Magnetic Resonance (1969). 50:50-63. 1982
- Heteronuclear organotransition-metal clusters: rational syntheses and fluxional behavior. Organometallics. 1:753-756. 1982
- ChemInform Abstract: ELECTRONIC STRUCTURE OF ZIRCONIUM TETRAHYDROBORATE AND HAFNIUM TETRAHYDROBORATE STUDIED BY PHOTOELECTRON SPECTROSCOPY AND LCAO-HFS CALCULATIONS. ChemInform. 13:no-no. 1982
- Electronic structure of zirconium tetrahydroborate and hafnium tetrahydroborate studied by photoelectron spectroscopy and LCAO-HFS calculations. Inorganic Chemistry: including bioinorganic chemistry. 21:793-798. 1982
- Molecular orbital investigation of the structure of some polyatomic cations and anions of the main-group elements. Inorganic Chemistry: including bioinorganic chemistry. 21:799-807. 1982
- ChemInform Abstract: ZIRCONIUM-91 NMR SPECTRUM OF TETRAKIS(TETRAHYDROBORATO)ZIRCONIUM: THE ZIRCONIUM-HYDROGEN COUPLING CONSTANT AS A PROBE FOR A FAST INTRAMOLECULAR PROCESS. ChemInform. 13:no-no. 1982
- A 61Ni NMR study of some d10 nickel complexes. Journal of Magnetic Resonance (1969). 46:158-162. 1982
- An unusual reaction of A π-complexed lithio-arene: the characterization and structure of μ-(2,2'-difluoro-5,5'-dimethylbenzophenone)bis(tricarbonylchromium(0)). Journal of Organometallic Chemistry. 224:267-283. 1982
- Racemization of chiral tetrahedral organotransition-metal clusters: a novel fluxional process. Organometallics. 1:225-227. 1982
- Zirconium-91 NMR spectrum of tetrakis(tetrahydroborato)zirconium: the zirconium-hydrogen coupling constant as a probe for a fast intramolecular process. Inorganic Chemistry: including bioinorganic chemistry. 20:3748-3750. 1981
- ChemInform Abstract: ZIRCONIUM-91 NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY: THE FIRST CHEMICAL STUDY. ChemInform. 12:no-no. 1981
- ChemInform Abstract: REARRANGEMENTS OF SULFURIMIDE ANIONS: 1,4-BIS(TRIMETHYLSILYL)HEXASULFUR-DIIMIDE FROM HEPTASULFURIMIDE. ChemInform. 12:no-no. 1981
- Carbon-13 nuclear magnetic resonance study of dinuclear iron carbonyl xanthate complexes: dynamic behaviour and local scrambling of the carbonyls at one iron atom. Dalton Transactions: an international journal of inorganic chemistry. 0:1278-1278. 1981
- Rearrangements of sulphurimide anions: 1,4-bis-(trimethylsilyl)hexasulphur-diimide from heptasulphurimide. Inorganica Chimica Acta. 53:L19-L20. 1981
- Transition metal complexes and the mechanism of pentalene formation. Inorganica Chimica Acta. 49:125-127. 1981
- Zirconium-91 nuclear magnetic resonance spectroscopy: the first chemical study. Inorganica Chimica Acta. 48:53-55. 1981
- Chemistry of free atoms and particles. Journal of Organometallic Chemistry. 202:C64-C64. 1980
- A 19F nuclear magnetic resonance study of a series of pentafluorochromarenes (C6F5X)Cr(C6H6). Journal of Organometallic Chemistry. 194:325-330. 1980
- A Carbon-13 NMR Spectroscopic Study of a Cr(CO)3-Stabilised Benzyl Anion. Journal of Organometallic Chemistry. 195:C9-C12. 1980
- Analysis of the vibrational spectra of C6H6CrC6F6 and C6D6CrC6F6 C6v sandwich compounds. Journal of Organometallic Chemistry. 195:193-201. 1980
- Diamagnetic anisotropy of metal-metal triple bonds. Inorganic Chemistry: including bioinorganic chemistry. 19:1392-1394. 1980
- A C-13 NMR SPECTROSCOPIC STUDY OF A CR(CO)3-STABILISED BENZYL ANION. Journal of Organometallic Chemistry. 195:C5-C8. 1980
- A F-19 NUCLEAR MAGNETIC-RESONANCE STUDY OF A SERIES OF PENTAFLUOROCHROMARENES (C6F5X)CR(C6H6). Journal of Organometallic Chemistry. 194:325-330. 1980
- Asymmetric induction via co-ordination to Cr(CO)3; nucleophilic attack on acyclic carbenium ions. Chemical Communications. 0:1110-1110. 1980
- Reactions of superoxide ion with hydrocarbons activated by the tricarbonylchromium unit. Chemical Communications. 0:643-643. 1980
- ChemInform Abstract: NICKEL ATOM PROMOTED DIMERIZATION OF DIMETHYLFULVENE. A FORMAL (6 + 6) CYCLOADDITION. ChemInform. 10:no-no. 1979
- Nickel atom promoted dimerization of dimethylfulvene. A formal [6 + 6] cycloaddition. Journal of the American Chemical Society. 101:2203-2204. 1979
- ChemInform Abstract: A CARBON-13 AND PROTON NUCLEAR MAGNETIC RESONANCE STUDY OF 5,6-DIHYDRO-2-METHYL-1,4-OXATHIIN DERIVATIVES. ChemInform. 10:no-no. 1979
- ChemInform Abstract: ANISOTROPIC RING-CARBON CHEMICAL SHIFTS IN ARENE CHROMIUM TRICARBONYL COMPLEXES. ChemInform. 10:no-no. 1979
- The chemistry of chromarenes: organic derivatives of 1,2,3,4,5-pentafluoro- and 1,2,4,5-tetrafluoro-chromarene. Journal of Organometallic Chemistry. 165:225-231. 1979
- Substituent effects and the stability of chromarenes. Journal of Organometallic Chemistry. 161:381-390. 1978
- Anisotropic ring-carbon chemical shifts in arene chromium tricarbonyl complexes. Journal of the American Chemical Society. 100:6902-6904. 1978
- Proton and carbon-13 nuclear magnetic resonance study of the atropisomeric forms of 4,4,9,17-tetramethyl-2,6-dithia[7.1]paracyclophane and its tetraoxide. Journal of Organic Chemistry. 43:3058-3060. 1978
- Local anisotropic contributions to 1H nuclear magnetic resonance shifts in alkynes. Canadian Journal of Chemistry. 56:959-961. 1978
- A carbon-13 and proton nuclear magnetic resonance study of 5,6-dihydro-2-methyl-1,4-oxathiin derivatives. Journal of the Chemical Society, Perkin Transactions 2. 0:1267-1267. 1978
- The synthesis and chemistry of 1,2,3,4,5-pentafluorochromarene; Electronic effect of a π-Cr(C6H6) moiety. Journal of Organometallic Chemistry. 141:85-97. 1977
- ChemInform Abstract: RING CURRENTS, LOCAL ANISOTROPY, AND THE PROBLEM OF THE OUT-OF-PLANE PROTONS- A REINVESTIGATION OF THE NUCLEAR MAGNETIC RESONANCE SPECTRUM OF (10)-PARACYCLOPHANE. ChemInform. 8:no-no. 1977
- Ring currents, local anisotropy, and the problem of the out-of-plane protons: a reinvestigation of the nuclear magnetic resonance spectrum of [10]-paracyclophane. Canadian Journal of Chemistry. 55:2575-2581. 1977
- ChemInform Abstract: NUCLEOPHILIC SUBSTITUTION REACTIONS IN FLUORINATED BIS(ARENE)CHROMIUM COMPLEXES. ChemInform. 7:no-no. 1976
- Nucleophilic substitution reactions in fluorinated bis(arene)chromium complexes. Journal of the American Chemical Society. 98:2271-2275. 1976
- Synthesis and ready metallation of (η-benzene)-(η-pentafluorobenzene)chromium. Chemical Communications. 0:155b-156. 1976
- 1,1′-Tetramethylethyleneferrocene : a direct synthesis from fulvenes and iron vapour. Chemical Communications. 0:771-772. 1975
- ChemInform Abstract: GERMANIUM ATOMS IN SYNTHESIS. ChemInform. 6:no-no. 1975
- Germanium atoms in synthesis. Inorganic Chemistry: including bioinorganic chemistry. 14:1209-1210. 1975
- Reactions of Transition Metal Atoms with Organic Substrates. Angewandte Chemie International Edition. 14:195-199. 1975
- Reaktionen von Übergangsmetallatomen mit organischen Verbindungen. Angewandte Chemie International Edition. 87:215-219. 1975
- ChemInform Abstract: SYNTHESIS AND (19)F NUCLEAR MAGNETIC RESONANCE SPECTRA OF FLUOROSUBSTITUTED BIS(ARENE)CHROMIUM COMPLEXES. ChemInform. 5:no-no. 1974
- Synthesis and 19F Nuclear Magnetic Resonance Spectra of Fluorosubstituted Bis(arene)chromium Complexes. Canadian Journal of Chemistry. 52:2439-2443. 1974
- ChemInform Abstract: CHROMIUM ATOMS IN ORGANOMETALLIC SYNTHESIS. ChemInform. 4:no-no. 1973
- ChemInform Abstract: CHEMIE UND DER KOHLE-LICHTBOGEN. ChemInform. 4:no-no. 1973
- Chromium atoms in organometallic synthesis. Journal of the American Chemical Society. 95:3337-3340. 1973
- Chemistry and the carbon arc. Accounts of Chemical Research. 6:97-105. 1973
- ChemInform Abstract: RK. VON NICKELATOMEN MIT UNGESAETTIGTEN KOHLENWASSERSTOFFEN. ChemInform. 4:no-no. 1973
- Corrigendum. Chemical Communications. 0:1348-1348. 1972
- Reactions of nickel atoms with unsaturated hydrocarbons. Chemical Communications. 0:1098-1098. 1972
- Studies in azide chemistry. Part IV. Synthesis of perhalogeno-β-iodoalkyl azides. Organic and Biomolecular Chemistry. 0:3971-3971. 1971
- ChemInform Abstract: DARST. VON FLUORIERTEN ALLENEN AUS ATOMAREM KOHLENSTOFF. Chemischer Informationsdienst. Organische Chemie. 1:no-no. 1970
- ChemInform Abstract: SYNTH. MIT MOLEKULAREM KOHLENSTOFF 2. MITT. GECL4, PCL3, S2CL2. Chemischer Informationsdienst. Organische Chemie. 1:no-no. 1970
- Fluoroalkylimido-complexes of group VIII metals. Journal of the Chemical Society D: Chemical Communications. 0:1265a-1265a. 1970
- Studies in azide chemistry. Part III. Polyfluorinated azides from 1H-and 2H-pentafluoropropene and perfluorobut-2-yne. Organic and Biomolecular Chemistry. 0:2172-2172. 1970
- Synthesis by use of molecular carbon. Part II. Germanium tetrachloride, phosphorus trichloride, and sulphur monochloride. Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry. 0:31-31. 1970
- Synthesis of fluorinated allenes using atomic carbon. Journal of the Chemical Society D: Chemical Communications. 0:1264-1264. 1970
- ChemInform Abstract: Cluster-Stabilized Cations: Syntheses, Structures, Molecular Dynamics and Reactivity. ChemInform. 27:no-no.
- ChemInform Abstract: Multidimensional NMR Study of Tris(indenyl)methylsilane: Molecular Dynamics Mapped onto a Hypercube.. ChemInform. 28:no-no.
- ChemInform Abstract: Reactions of Dimethoxycarbene with Cyclic Perchlorinated Olefins and Ketones.. ChemInform. 30:no-no.
- ChemInform Abstract: Slowed Tripodal Rotation in Arene-Chromium Complexes: Steric and Electronic Barriers.. ChemInform. 25:no-no.
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chapter
- The Biological Target Potential of Organometallic Steroids. 43-84. 2014
- Metal atoms in organometallic synthesis. 539-574. 2010
- Chromium compounds with CO or isocyanides. 201-289. 2007
- Chromium Compounds with CO or Isocyanides. 201-289. 2007
- A Novel Field of Research: Bioorganometallic Chemistry, Origins, and Founding Principles. 1-37. 2005
- Organometallic Migrations over Clusters and Surfaces. 203-216. 1995
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conference paper
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- Synthesis and biological activity of ferrocenyl derivatives of the non-steroidal antiandrogens flutamide and bicalutamide. Journal of Organometallic Chemistry. 1049-1056. 2011
- McMurry reactions of (η5-acetylcyclopentadienyl) cobalt-(η4-tetraphenylcyclobutadiene) with benzophenone: ketone couplings and a pinacol/pinacolone rearrangement. Journal of Organometallic Chemistry. 4683-4690. 2004
- Fluxional behavior of sterically hindered cyclopentadienone rhodium acetylacetonate complexes.. ACS National Meeting Book of Abstracts. U549-U549. 2001
- (Metal) complex solutions to some synthetic (silicon) problems.. ACS National Meeting Book of Abstracts. U82-U83. 1998
- Organometallic migrations over clusters and surfaces - Symmetry-allowed shifts via aromatic transition states. SYNERGY BETWEEN DYNAMICS AND REACTIVITY AT CLUSTERS AND SURFACES. 203-216. 1995
- FLUXIONAL PROCESSES IN CO3(CO)9CR CLUSTERS - A HIGH-FIELD NMR-STUDY. ACS National Meeting Book of Abstracts. 273-INOR. 1988
- THE FORMATION OF CHIRAL MIXED METAL-CLUSTERS USING NATURAL-PRODUCTS AS TEMPLATES. ACS National Meeting Book of Abstracts. 562-INOR. 1988
- NMR CHARACTERIZATION OF 2H-PYRANS SYNTHESIZED VIA THE CONDENSATION AND CYCLIZATION OF FLUORINATED DIKETONES IN THE PRESENCE OF A SILICON(IV) COMPOUND. ACS National Meeting Book of Abstracts. 71-71. 1979