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One-pot chemoenzymatic preparation of coenzyme A...
Journal article

One-pot chemoenzymatic preparation of coenzyme A analogues

Abstract

A rapid and stoichiometric method for the synthesis of analogues of coenzyme A is described. The method links the enzymes pantothenate kinase, phosphopantotheine adenylyltransferase, and dephosphocoenzyme A kinase in vitro to generate a variety of CoA analogues from chemically synthesized pantothenic acid derivatives. The Escherichia coli CoA biosynthetic enzymes were overexpressed as hexa-histidine-tagged proteins, providing an abundant source …

Authors

Nazi I; Koteva KP; Wright GD

Journal

Analytical Biochemistry, Vol. 324, No. 1, pp. 100–105

Publisher

Elsevier

Publication Date

1 2004

DOI

10.1016/j.ab.2003.09.005

ISSN

0003-2697