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Near-Edge X-ray Absorption Fine Structure...
Journal article

Near-Edge X-ray Absorption Fine Structure Spectroscopy of MDI and TDI Polyurethane Polymers

Abstract

The sensitivity of near-edge X-ray absorption fine structure (NEXAFS) to differences in key chemical components of polyurethane polymers is presented. Carbon 1s NEXAFS spectra of polyurethane polymers made from 4,4‘-methylene di-p-phenylene isocyanate (MDI) and toluene diisocyanate (TDI) isocyanate monomers illustrate that there is an unambiguous spectroscopic fingerprint for distinguishing between MDI-based and TDI-based polyurethane polymers. …

Authors

Urquhart SG; Smith AP; Ade HW; Hitchcock AP; Rightor EG; Lidy W

Journal

The Journal of Physical Chemistry B, Vol. 103, No. 22, pp. 4603–4610

Publisher

American Chemical Society (ACS)

Publication Date

June 1, 1999

DOI

10.1021/jp990059w

ISSN

1520-6106