Diagrams can be constructed in stress space which show, for metals and alloys, the competition between the processes which lead to fracture. These include yield, necking, void nucleation, ductile fracture, brittle grain-boundary fracture, cleavage, shear fracture, and plastic rupture. Simplified diagrams are constructed for E.T.P. copper, α-brass, two steels and an aluminium alloy. The diagrams show how the fracture mechanism changes with stress state and help rationalize a number of apparently conflicting observations. They have application in predicting the behaviour of metals under complex stress states.