Journal article
Siloxane -supported organometallic compounds and their catalytic activities for the hydrosilylation of vinylsilanes and dienes
Abstract
Two different classes of silicone-modified ligands were prepared: nitrile derivatives, 4'-[3-(organosilyl)propoxy]biphenyl-4-carbonitrile R'3SiC3H6OC6H4C6H4CN (R'3Si- = a: Me3SiOSiMe2-, b: (Me(3)SiO)2SiMe-, c: Me3SiO(Me2SiO)3SiMe2-, d: Me3SiO(Me2SiO)25SiMe2-); and, pyridine derivatives, isonicotinic acid 2-methoxy-4-[3-(organosilyl)propyl]phenyl ester R'3SiC3H6Ph(O)MeOCOC5H4N . Compounds and were bound to Pd and Pt using ligand substitution …
Authors
Amako M; Schinkel J; Freiburger L; Brook MA
Journal
Dalton Transactions, Vol. 0, No. 1, pp. 74–81
Publisher
Royal Society of Chemistry (RSC)
Publication Date
2005
DOI
10.1039/b411123k
ISSN
1477-9226