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Liquid Triarylamines: The Scope and Limitations of...
Journal article

Liquid Triarylamines: The Scope and Limitations of Piers–Rubinsztajn Conditions for Obtaining Triarylamine–Siloxane Hybrid Materials

Abstract

New liquid triarylamine-siloxane hybrid materials are produced using the Piers-Rubinsztajn reaction. Under mild conditions, liquid analogues of conventional and commonly crystalline triarylamines are easily synthesized from readily available or accessible intermediates. Using a diverse selection of triarylamines, we explored the effects of siloxane group and substitution pattern on the physical properties of these materials, and we have …

Authors

Kamino BA; Mills B; Reali C; Gretton MJ; Brook MA; Bender TP

Journal

The Journal of Organic Chemistry, Vol. 77, No. 4, pp. 1663–1674

Publisher

American Chemical Society (ACS)

Publication Date

February 17, 2012

DOI

10.1021/jo2020906

ISSN

0022-3263