Theory of Polygonal Phases Self-Assembled from T‑Shaped Liquid Crystalline Molecules

Extensive experimental studies have shown that numerous ordered phases can be formed via the self-assembly of T-shaped liquid crystalline molecules (TLCMs) composed of a rigid backbone, two flexible end chains, and a flexible side chain. However, a comprehensive understanding of the stability and formation mechanisms of these intricately nanostructured phases remains incomplete. Here, we fill this gap by carrying out a theoretical study of the …