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Communication: A case where the hard/soft...
Journal article

Communication: A case where the hard/soft acid/base principle holds regardless of acid/base strength

Abstract

We show that the hard∕soft acid∕base principle holds when electron-transfer effects are dominant and the weaker acid and stronger base are harder than the other acidic and basic reagents. In this case the preference of strong acids for strong bases and weak acids for weak bases reinforces the preference of hard acids for hard bases and soft acids for soft bases.

Authors

Ayers PW; Cárdenas C

Journal

The Journal of Chemical Physics, Vol. 138, No. 18,

Publisher

AIP Publishing

Publication Date

May 14, 2013

DOI

10.1063/1.4805083

ISSN

0021-9606