Journal article
A Zwitterionic Palladium(II) η3-Boratoxypentadienyl Complex: Cooperative Activation of Dibenzylideneacetone between Palladium and a Phosphine/Thioether/Borane Ligand
Abstract
A free phosphine/thioether/borane ligand (5) suitable to position a Lewis acidic borane in close proximity to a coordinated late transition metal has been prepared. Reaction with 0.5 [Pd2(dba)3] gave a zwitterionic palladium(II) η3-boratoxypentadienyl complex with the empirical formula [Pd(dba)(5)].
Authors
Emslie DJH; Blackwell JM; Britten JF; Harrington LE
Journal
Organometallics, Vol. 25, No. 10, pp. 2412–2414
Publisher
American Chemical Society (ACS)
Publication Date
May 1, 2006
DOI
10.1021/om0602052
ISSN
0276-7333