Enhanced Exfoliation of Organoclay in Partially End‐Functionalized Non‐Polar Polymer

Abstract We found that enhanced exfoliation of clay up to 20 wt.‐% in non‐polar polybutadiene (PB) if the PB was blended with a relatively small fraction of hydroxyl‐terminated PB (HTPB). The choice of an intermediate polymer composition to enhance exfoliation was motivated by theoretical predictions of end‐functionalizing effects of Balazs, Farmer, and coworkers. A combination of X‐ray diffraction and rheological measurements were used to …