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Quantitative description of analyte migration...
Journal article

Quantitative description of analyte migration behavior based on dynamic complexation in capillary electrophoresis with one or more additives

Abstract

A comprehensive theory is proposed to describe the migration behavior of analytes in capillary electrophoresis (CE) when one or more additives are present in the buffer solution. This theory amalgamates and extends the previous work done by others. The capacity factor (k') in this theory is defined as the product of the equilibrium constant and the additive concentration, thus, k' changes linearly with additive concentration. The net …

Authors

Peng X; Bowser MT; Britz‐McKibbin P; Bebault GM; Morris JR; Chen DDY

Journal

Electrophoresis, Vol. 18, No. 5, pp. 706–716

Publisher

Wiley

Publication Date

January 1997

DOI

10.1002/elps.1150180509

ISSN

0173-0835