Journal article
η3‐Vinylborane Complexes of Platinum and Nickel: Borataallyl‐ and Alkyl/Borataalkene‐Like Coordination Modes
Abstract
Anyone for pi? The vinylborane PhHCCH‐B(C6F5)2 reacts with zero‐valent Group 10 transition‐metal precursors to form η3‐vinylborane complexes. The platinum tri‐tert‐butylphosphine complex exhibits an η3‐borataallyl‐like coordination mode whereas the nickel bis(triphenylphosphine) complex tends towards alkyl/borataalkene coordination.
Authors
Kolpin KB; Emslie DJH
Journal
Angewandte Chemie International Edition, Vol. 49, No. 15, pp. 2716–2719
Publisher
Wiley
Publication Date
April 2010
DOI
10.1002/anie.200906931
ISSN
1433-7851