Roughening of Gold Atomic Steps Induced by Interaction with Tetrahydrofuran

Exposure of a clean gold surface to tetrahydrofuran (THF) under ambient conditions was observed to cause roughening of atomic step edges. This change was followed in situ using a scanning tunneling microscope during the exposure of a gold surface to a controlled stream of THF vapor. THF is a common solvent used in depositing molecules, self-assembled monolayers, and polymer films on surfaces, in electrochemistry, and in chemical reactions. …