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Reorientation phenomena in imidazolium methyl...
Journal article

Reorientation phenomena in imidazolium methyl sulfonate as probed by advanced solid-state NMR

Abstract

Evidence for reorientation of imidazolium rings in imidazolium methylsulfonate is demonstrated using solid-state NMR. This material is a model system for exciting new proton-conducting materials based on imidazole. Two advanced NMR methods, including 1H-13C and 1H-15N recoupled polarization transfer with dipolar sideband pattern analysis and analysis of the coalescence of 13C lineshapes are used to characterize the ring reorientation. The …

Authors

Goward GR; Saalwächter K; Fischbach I; Spiess HW

Journal

Solid State Nuclear Magnetic Resonance, Vol. 24, No. 2-3, pp. 150–162

Publisher

Elsevier

Publication Date

September 2003

DOI

10.1016/s0926-2040(03)00043-2

ISSN

0926-2040