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The use of 6 Li{ 7 Li}-REDOR NMR spectroscopy to...
Journal article

The use of 6 Li{ 7 Li}-REDOR NMR spectroscopy to compare the ionic conductivities of solid-state lithium ion electrolytes

Abstract

Garnet-like solid-state electrolyte materials for lithium ion batteries are promising replacements for the currently-used liquid electrolytes. This work compares the temperature dependent Li(+) ion hopping rate in Li6BaLa2M2O12 (M = Ta, Nb) using solid-state (6)Li{(7)Li}-REDOR NMR. The slope of the (6)Li{(7)Li}-REDOR curve is highly temperature dependent in these two phases, and a comparison of the changes of the REDOR slopes as a function of …

Authors

Spencer TL; Plagos NW; Brouwer DH; Goward GR

Journal

Physical Chemistry Chemical Physics, Vol. 16, No. 6, pp. 2515–2526

Publisher

Royal Society of Chemistry (RSC)

Publication Date

February 14, 2014

DOI

10.1039/c3cp55132f

ISSN

1463-9076