Journal article
Acid catalysed stereomutations about the C(2)–C(3) bond of 3-aryl-1-methoxyallyl cations. Dication formation by oxygen protonation
Abstract
The thermally induced cis to trans isomerization of 3-aryl-1-methoxyallyl cations in superacid media is shown to occur by formation of an intermediate O-protonated dication.
Authors
Blackburn C; Childs RF
Journal
Chemical Communications, Vol. 0, No. 13, pp. 812–813
Publisher
Royal Society of Chemistry (RSC)
Publication Date
1984
DOI
10.1039/c39840000812
ISSN
1359-7345