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Determination of 4‐hydroxyproline‐2‐epimerase...
Journal article

Determination of 4‐hydroxyproline‐2‐epimerase activity by capillary electrophoresis: A stereoselective platform for inhibitor screening of amino acid isomerases

Abstract

Isomerases involved in the metabolism of D/L-amino acids represent promising therapeutic targets for treatment of disease. Herein, we report a tunable platform for the assessment of enzymatic kinetics involving amino acid isomerization by CE that offers improved selectivity and sensitivity over traditional methods. Enzyme activity and competition assays were evaluated for various hydroxyproline diastereoisomers, proline enantiomers and their …

Authors

Gavina JMA; White CE; Finan TM; Britz‐McKibbin P

Journal

Electrophoresis, Vol. 31, No. 16, pp. 2831–2837

Publisher

Wiley

Publication Date

August 2010

DOI

10.1002/elps.201000187

ISSN

0173-0835