Coordination chemistry and structural rearrangements of the Me 2 PCH 2 AlMe 2 ambiphilic ligand

Reaction of 2 equivalents of (Me₂PCH₂AlMe₂)₂ with [{RhCl(cod)}₂] (cod = 1,5-cyclooctadiene) afforded [{κ²P,P-(Me₃Al)ClMeAl(CH₂PMe₂)₂}Rh(cod)] (1), which features a κ²-coordinated bis(phosphino)aluminate anion. In compound 1, an Al-Cl substituent bridges to a molecule of AlMe₃, which could be removed in vacuo to provide [{κ²P,P-ClMeAl(CH₂PMe₂)₂}Rh(cod)] (2). By contrast, reaction of 1 equiv. of (Me₂PCH₂AlMe₂)₂ with [{RhCl(cod)}₂] yielded …