Journal article
Spin-Gap Formation and Thermal Structural Studies in Reduced Hybrid Layered Vanadates
Abstract
Reduced layered M(C4H4N2)V4O10 ((I, M = Co; II, M = Ni; III, M = Zn); C4H4N2 = pyrazine, pyz) hybrid solids were synthesized via hydrothermal reactions at 200-230 degrees C, and their structures determined by single-crystal X-ray diffraction (Cmcm, No. 63, Z = 4; a = 14.311(2), 14.2372(4), 14.425(1) A; b = 6.997(1), 6.9008(2), 6.9702(6) A; and c = 11.4990(8), 11.5102(3), 11.479(1) A; for I, II, and III, respectively). All three solids are …
Authors
Yan B; Luo J; Dube P; Sefat AS; Greedan JE; Maggard PA
Journal
Inorganic Chemistry, Vol. 45, No. 13, pp. 5109–5118
Publisher
American Chemical Society (ACS)
Publication Date
June 1, 2006
DOI
10.1021/ic0604563
ISSN
0020-1669