MOF‐Based Hierarchically Porous Monoliths Prepared via High Internal Phase Emulsion Template: Morphology, Thermal Stability, Mechanical Property, and MOF Accessibility

Abstract In this work, hierarchically macro/microporous monolithic MOF composite materials are fabricated through the HIPE template. The effects of MOF loading on the pore structure, thermal stability, mechanical property, and MOF accessibility are systematically investigated. As the MOF loading increased, the average pore size and mechanical property decreased while the thermal stability increased. Meanwhile, when the MOF loading is low, the …