Journal article
Influence of pressure on the lengths of chemical bonds
Abstract
An expression to describe the force that a chemical bond exerts on its terminal atoms is proposed, and is used to derive expressions for the bond force constant and bond compressibility. The unknown parameter in this model, the effective charge on the atoms that form the bond, is determined by comparing the derived force constants with those obtained spectroscopically. The resultant bond compressibilities are shown to generally agree well with …
Authors
Brown ID; Klages P; Skowron A
Journal
Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, Vol. 59, No. 4, pp. 439–448
Publisher
International Union of Crystallography (IUCr)
Publication Date
August 1, 2003
DOI
10.1107/s0108768103010474
ISSN
2052-5192