Journal article
Tetra-μ-acetato-κ8O:O′-bis[(2-benzylidene-6,7-dihydro-5H-thiazolo[3,2-a]pyrimidin-3-one-κN)cobalt(II)]
Abstract
The title compound, [Co2(C2H3O2)4(C13H12N2OS)2], is a binuclear complex, which occupies a special position at an inversion centre. Each Co atom has a distorted octahedral coordination, which involves four O atoms of four μ-acetate groups [Co—O = 1.9617 (19)–1.977 (2) Å] and the N atom of the 2-benzylidene-6,7-dihydro-5H-thiazolo[3,2-a]pyrimidin-3-one ligand [Co—N = 2.214 (2) Å]; the coordination octahedron is completed by the Co—Co bond of …
Authors
Wang D-H; Li X; Liu X-G
Journal
Acta Crystallographica Section E: Crystallographic Communications, Vol. 60, No. 5, pp. m703–m704
Publisher
International Union of Crystallography (IUCr)
Publication Date
May 15, 2004
DOI
10.1107/s1600536804010049
ISSN
1600-5368