Journal article
Synthesis of methacrylate macromonomers using silica gel supported atom transfer radical polymerization
Abstract
A silica gel supported CuBr‐hexamethyltriethylenetetramine (HMTETA) (SG‐CuBr/HMTETA) catalyst system was developed for the synthesis of poly‐(methyl methacrylate) (PMMA) and poly(dimethylaminoethyl methacrylate) (polyDMAEMA) macromonomers with terminal vinyl or allyl group by atom transfer radical polymerization (ATRP). Catalyzed by SG‐CuBr/HMTETA and with vinyloxyethyl 2‐bromoisobutyrate (VBIB) or allyl 2‐bromoisobutyrate (ABIB) as initiator, …
Authors
Shen Y; Zhu S; Zeng F; Pelton R
Journal
Macromolecular Chemistry and Physics, Vol. 201, No. 13, pp. 1387–1394
Publisher
Wiley
Publication Date
August 1, 2000
DOI
10.1002/1521-3935(20000801)201:13<1387::aid-macp1387>3.0.co;2-7
ISSN
1022-1352