μSR study of spin freezing and persistent spin dynamics in NaCaNi2F7

A new pyrochlore compound, NaCaNi₂F₇, was recently synthesized and has a single magnetic site with spin-1 Ni²⁺ . We present zero field and longitudinal field muon spin rotation (μSR) measurements on this pyrochlore. Density functional theory calculations show that the most likely muon site is located between two fluorine ions, but off-centre. A characteristic F-μ-F muon spin polarization function is observed at high temperatures where Ni spin …