Regioselective Ylide Formation on...

Regioselective Ylide Formation on Acetal-Functionalized Trialkyl Phosphonium Salts: Extending the Scope of Carbonyl Homologation

Abstract

The discovery of a complex-induced proximity effect and scope of regioselective ylide formation on acetal- and ketal-functionalized trialkylphosphine-derived phosphonium salts is explored as a route to homologated unsaturated carbonyl derivatives.

Authors

Narayanappa A; Hurem D; McNulty J

Journal

Synlett, Vol. 28, No. 20, pp. 2961–2965

Publisher

Thieme

Publication Date

December 18, 2017

DOI

10.1055/s-0036-1588551

ISSN

0936-5214

Associated Experts

James Mcnulty

Professor, Faculty of Science

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Labels

Fields of Research (FoR)

3405 Organic chemistry 34 Chemical Sciences 3404 Medicinal and biomolecular chemistry

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