Journal article
Xe3OF3 +, a Precursor to a Noble-Gas Nitrate; Syntheses and Structural Characterizations of FXeONO2, XeF2·HNO3, and XeF2·N2O4
Abstract
Xenon fluoride nitrate has been synthesized by reaction of NO(2)F with [FXeOXeFXeF][AsF(6)] at -50 °C. It was characterized in SO(2)ClF and CH(3)CN solutions by low-temperature (14)N, (19)F, and (129)Xe NMR spectroscopy and in the solid state by low-temperature Raman spectroscopy (-160 °C) and single-crystal X-ray diffraction (-173 °C). The reactions were carried out using natural abundance and (18)O-enriched [FXeOXeFXeF][AsF(6)] and (15)NO(2)F …
Authors
Moran MD; Brock DS; Mercier HPA; Schrobilgen GJ
Journal
Journal of the American Chemical Society, Vol. 132, No. 39, pp. 13823–13839
Publisher
American Chemical Society (ACS)
Publication Date
October 6, 2010
DOI
10.1021/ja105618w
ISSN
0002-7863