Journal article
Syntheses and Multi-NMR Study of fac- and mer-OsO3F2(NCCH3) and the X-ray Crystal Structure (n = 2) and Raman Spectrum (n = 0) of fac-OsO3F2(NCCH3)·nCH3CN
Abstract
Dissolution of the infinite chain polymer, (OsO(3)F(2))(infinity), in CH(3)CN solvent at -40 degrees C followed by solvent removal under vacuum at -40 degrees C yielded fac-OsO(3)F(2)(NCCH(3)).nCH(3)CN (n >/= 2). Continued pumping at -40 degrees C with removal of uncoordinated CH(3)CN yielded fac-OsO(3)F(2)(NCCH(3)). Both fac-OsO(3)F(2)(NCCH(3)).nCH(3)CN and fac-OsO(3)F(2)(NCCH(3)) are yellow-brown solids and were characterized by …
Authors
Hughes MJ; Gerken M; Mercier HPA; Schrobilgen GJ
Journal
Inorganic Chemistry, Vol. 49, No. 11, pp. 4768–4780
Publisher
American Chemical Society (ACS)
Publication Date
June 7, 2010
DOI
10.1021/ic100383p
ISSN
0020-1669