Journal article
XeOF2, F2OXeN≡CCH3, and XeOF2·nHF: Rare Examples of Xe(IV) Oxide Fluorides
Abstract
The syntheses of XeOF2, F2OXeNCCH3, and XeOF2.nHF and their structural characterizations are described in this study. All three compounds are explosive at temperatures approaching 0 degrees C. Although XeOF2 had been previously reported, it had not been isolated as a pure compound. Xenon oxide difluoride has now been characterized in CH3CN solution by 19F, 17O, and 129Xe NMR spectroscopy. The solid-state Raman spectra of XeOF2, F2OXeNCCH3, and …
Authors
Brock DS; Bilir V; Mercier HPA; Schrobilgen GJ
Journal
Journal of the American Chemical Society, Vol. 129, No. 12, pp. 3598–3611
Publisher
American Chemical Society (ACS)
Publication Date
March 1, 2007
DOI
10.1021/ja0673480
ISSN
0002-7863