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Quantification of the Ti oxidation state in...
Conference

Quantification of the Ti oxidation state in BaTi1−xNbxO3 compounds

Abstract

The Ti oxidation state of a series mixed-valence BaTi1−xNbxO3 compound (where x=0.002, 0.004, 0.02, 0.10, 0.20 and 0.50) is investigated using high resolution electron energy loss spectroscopy (EELS). The energy loss near edge structure (ELNES) of the Ti-L2,3 and O-K edges was recorded with high energy resolution. The fraction of Ti4+ and Ti3+ components is determined in each compound by linear profile fitting with Ti4+ and Ti3+ standard …

Authors

Shao Y; Maunders C; Rossouw D; Kolodiazhnyi T; Botton GA

Volume

110

Pagination

pp. 1014-1019

Publisher

Elsevier

Publication Date

7 2010

DOI

10.1016/j.ultramic.2010.05.006

Conference proceedings

Ultramicroscopy

Issue

8

ISSN

0304-3991