Journal article
Modeling stable free‐radical polymerization
Abstract
A kinetic model has been developed for stable free‐radical polymerization (SFRP) processes by using the method of moments. This model predicts monomer conversion, number‐average molecular weight, and polydispersity of molecular weight distribution. The effects of the concentrations of initiator, stable radical, and monomer, as well as the rate constants of initiation, propagation, termination, transfer, and the equilibrium constant between …
Authors
Zhu S
Journal
Journal of Polymer Science Part B Polymer Physics, Vol. 37, No. 18, pp. 2692–2704
Publisher
Wiley
Publication Date
September 15, 1999
DOI
10.1002/(sici)1099-0488(19990915)37:18<2692::aid-polb13>3.0.co;2-i
ISSN
0887-6266