Journal article
Continuous solution copolymerization of ethylene and octene‐1 with constrained geometry metallocene catalyst
Abstract
The solution copolymerization of ethylene (1) with octene‐1 (2) in Isopar E using constrained geometry catalyst system, [C5Me4(SiMe2NtBu)]TiMe2 (CGC‐Ti)/tris(pentafluorophenyl)boron (TPFPB)/modified methylaluminoxane (MMAO), has been carried out in a high‐temperature, high‐pressure continuous stirred‐tank reactor (CSTR) at 140°C, 500 psig and with a mean residence time of 4 min. A series of copolymer samples with octene‐1 content up to 0.337 …
Authors
Wang W; Kolodka E; Zhu S; Hamielec AE
Journal
Journal of Polymer Science Part A Polymer Chemistry, Vol. 37, No. 15, pp. 2949–2957
Publisher
Wiley
Publication Date
August 1, 1999
DOI
10.1002/(sici)1099-0518(19990801)37:15<2949::aid-pola28>3.0.co;2-w
ISSN
0887-624X