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Thermodynamic stability of the lithium zirconates...
Journal article

Thermodynamic stability of the lithium zirconates and lithium yttrate

Abstract

The thermodynamic data of the lithium zirconates (Li2ZrO3, Li6Zr2O7,Li4ZrO4 and Li8ZrO6) were calculated based on the Neumann-Kopp rule and the third law. The equilibrium lithium oxide vapor pressures and lithium loss values due to evaporation at different temperatures and in different environments were obtained. Thermal decomposition of Li8ZrO6 was assessed by theoretical calculations and weight loss and XRD experiments. The experimental …

Authors

Zou Y; Petric A

Journal

Journal of Physics and Chemistry of Solids, Vol. 55, No. 6, pp. 493–499

Publisher

Elsevier

Publication Date

June 1994

DOI

10.1016/0022-3697(94)90154-6

ISSN

0022-3697