Sintering and Microstructure Modification of Mullite/Zirconia Composites Derived from Silica‐Coated Alumina Powders

This paper addresses the densification and microstructure development during firing of mullite/zirconia composites made from silica‐coated‐alumina (SCA) microcomposite powders. Densification occurs in two stages: in the presence of a silica–alumina mixture and after conversion to mullite. The first stage of densification occurs through transient viscous phase sintering (TVS). This is best promoted by rapid heating, which delays the crystallization of silica to higher temperatures. A further sintering stage is observed following mullitization. The introduction of seeds promotes solid‐state sintering, most probably due to refinement of the mullite matrix. For seed concentrations up to about 1% the sintering kinetics depend on seed concentration. This suggests that nucleation still remains the rate‐controlling mullitization step. Above this concentration the reaction becomes growth controlled. Introduction of seeds also promotes direct mullitization without transient zircon formation that was observed in a previous study of the same process without seeding. Seeding also promotes the development of elongated grains by way of a solid‐state recrystallization process.