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Inner-Shell Excitation Spectroscopy of Polymer and...
Journal article

Inner-Shell Excitation Spectroscopy of Polymer and Monomer Isomers of Dimethyl Phthalate

Abstract

The C 1s X-ray absorption spectra (XAS) of poly(diallyl phthalate), poly(diallyl isophthalate), and poly(ethylene terephthalate) (PET) have been recorded using transmission detection. The phthalate segments of these polymers are isomers with different patterns of substitution (ortho, meta, para) of the methyl carboxylate groups on the phenyl ring. The C 1s and O 1s electron energy loss spectra (EELS) of the corresponding isomeric monomers, …

Authors

Urquhart SG; Hitchcock AP; Smith AP; Ade H; Rightor EG

Journal

The Journal of Physical Chemistry B, Vol. 101, No. 13, pp. 2267–2276

Publisher

American Chemical Society (ACS)

Publication Date

March 1, 1997

DOI

10.1021/jp963419d

ISSN

1520-6106