Journal article
Inner shell spectroscopy of the carbon—sulfur bond
Abstract
The oscillator strengths for S 1s excitation of thiols (CH3SH, C2H5SH, C6H5SH) and thioethers (CH3SCH3, C2H5SC2H5 and C6H5SCH3) have been derived from ionization yield spectra recorded by synchrotron radiation. These spectra have been analyzed by comparison among the series. The discrete regions of each spectrum are dominated by a feature attributed to S 1s→σ*(SC) transitions. An S 1s→σ*(SH) transition has been identified in the thiol spectra …
Authors
Dezarnaud C; Tronc M; Hitchcock AP
Journal
Chemical Physics, Vol. 142, No. 3, pp. 455–462
Publisher
Elsevier
Publication Date
April 1990
DOI
10.1016/0301-0104(90)80040-5
ISSN
0301-0104