Inner shell spectroscopy of (η⁵-C₅H₅)₂TiCl₂, (η⁵-C₅H₅)TiCl₃, and TiCl₄ Journal Articles

abstract

• Oscillator strengths for C 1s excitation of gas phase Cp2TiCl2 and CpTiCl3 (Cp = η5-C5H5), and Cl 2p and Ti 2p excitation of gas phase Cp2TiCl2, CpTiCl3, and TiCl4 have been derived from electron energy loss spectra recorded under electric dipole scattering conditions. The C 1s spectra are interpreted with the aid of semiempirical extended Hückel calculations and comparisons with the C 1s spectra of other cyclopentadienyl complexes. The Ti 2p spectra are interpreted using the extended Hückel results and comparisons with atomic multiplet–crystal field calculations for Ti4+ taken from the literature.

authors

• Wen, AT
• Hitchcock, Adam Percival

status

• published 

publication date

• October 1, 1993

has subject area

• 03 Chemical Sciences (FoR)
• General Chemistry (Science Metrix)

published in

• Canadian Journal of Chemistry  Journal

keywords

• CYCLOPENTADIENYL LIGAND
• Chemistry
• Chemistry, Multidisciplinary
• ELECTRONIC EXCITATION
• ENERGY-LOSS SPECTROSCOPY
• EXCITATION-SPECTRA
• GAS-PHASE
• OCTAHEDRAL SYMMETRY
• ORGANOMETALLIC COMPOUNDS
• PHOTOELECTRON-SPECTRA
• Physical Sciences
• Science & Technology
• TRANSITION-METAL COMPOUNDS
• X-RAY-ABSORPTION

Digital Object Identifier (DOI)

• 10.1139/v93-204

start page

• 1632

end page

• 1644

volume

• 71

issue

• 10