Effects of polymer molecular weight and filler particle size on flow behavior of wood polymer composites

AbstractThe influence of polymer matrix molecular weight and filler particle size on rheological properties and extrudate distortions of metallocene polyethylene (mPE)/wood flour (WF) composites has been investigated by rotational and capillary rheometers. It was found that at low shear rates smaller filler particles provide higher shear viscosity than the larger sized filler. At high shear rates and WF loadings above 30 wt%, the effect of particle size on the melt flow properties becomes negligible. The relative increase of the storage modulus with decreasing particle size is more pronounced in the case of low molecular weight polymer matrix than that in higher molecular weight polyethylene based composites. The wood filled polyethylenes exhibit extrudate surface defects, which are complex function of the shear rate, polymer matrix molecular weight, and filler particle size. Increasing the shear rate results in pressure oscillations and spurt‐flow. It was also observed that the evolution of the extrudate surface tearing is strongly dependent on the pressure during a single pressure oscillation cycle in the spurt flow regime. POLYM. COMPOS., 2008. © 2008 Society of Plastics Engineers

Effects of polymer molecular weight and filler particle size on flow behavior of wood polymer composites Journal Articles