Interactions of Hydrophobically Modified Polyvinylamine with Pluronic Triblock Copolymer Micelles

The heats associated with the addition of triblock copolymers of ethylene oxide and propylene oxide (PEO-PPO-PEO pluronics) to solutions of linear polyvinylamine, with N-substituted pendant octyl groups (HMPVAm), were measured as functions of pH and pluronic structure. The interactions were exothermic with the overall enthalpy decreasing with increasing pH from 5 to 10. Surprisingly, the heat effect increased with increasing pluronic …