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What Is an Atom in a Molecule?
Journal article

What Is an Atom in a Molecule?

Abstract

The derivation of the Hirshfeld atoms in molecules from information theory is clarified. The importance for chemistry of the concept of atoms in molecules (AIM) is stressed, and it is argued that this concept, while highly useful, constitutes a noumenon in the sense of Kant.

Authors

Parr RG; Ayers PW; Nalewajski RF

Journal

The Journal of Physical Chemistry A, Vol. 109, No. 17, pp. 3957–3959

Publisher

American Chemical Society (ACS)

Publication Date

May 1, 2005

DOI

10.1021/jp0404596

ISSN

1089-5639