Journal article
A variational principle for the electron density using the exchange hole & its implications for N-representability
Abstract
We show that the exchange hole determines both the electron density and the number of electrons through a variational principle. An eigenvalue condition related to the exchange hole is also derived. These results provide N-representability constraints on the exchange hole and limit the forms of model exchange holes. Whether a similar principle holds for the exchange-correlation hole is an open question.
Authors
Ayers PW; Cuevas-Saavedra R; Chakraborty D
Journal
Physics Letters A, Vol. 376, No. 6-7, pp. 839–844
Publisher
Elsevier
Publication Date
January 2012
DOI
10.1016/j.physleta.2012.01.028
ISSN
0375-9601