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Assessment of the March-Santamaria kinetic energy...
Journal article

Assessment of the March-Santamaria kinetic energy pair-density functional

Abstract

The quality of the March-Santamaria kinetic energy function for the spin-resolved electron pair density is assessed. While the March-Santamaria functional is exact for all pair densities that arise from a single Slater determinant wavefunction, its value tends to decrease (instead of increase) with increase correlation.

Authors

Chakraborty D; Ayers PW

Journal

Journal of Mathematical Chemistry, Vol. 49, No. 8,

Publisher

Springer Nature

Publication Date

September 2011

DOI

10.1007/s10910-011-9861-0

ISSN

0259-9791