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The chemical theory of valence
Journal article

The chemical theory of valence

Abstract

Relaxing the restriction that valence can only adopt integer values removes the distinction between ionic and covalent bonds, resulting in a simple and powerful valence theory using the concept of the bonding strength of an element, defined as the ratio of its atomic valence to its average coordination number. Bonding strength, closely related to electronegativity, determines which atoms form stable bonds and the chemical properties of the …

Authors

Brown ID

Journal

Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, Vol. 81, No. 2, pp. 164–167

Publisher

International Union of Crystallography (IUCr)

Publication Date

April 1, 2025

DOI

10.1107/s2052520625000022

ISSN

2052-5192