Influence of Fuel Properties on the Light Absorption of Fresh and Laboratory-Aged Atmospheric Brown Carbon Produced from Realistic Combustion of Boreal Peat and Spruce Foliage

Climate change has exacerbated fire activity in the boreal region. Consequently, smoldering boreal peatland fires are an increasingly important source of light-absorbing atmospheric organic carbon ("brown carbon"; BrC). To date, however, BrC from this source remains largely unstudied, which limits our ability to predict its climate impact. Here, we use size-exclusion chromatography coupled with diode array UV-vis detection to examine the molecular-size-dependent light absorption properties of fresh and photoaged aqueous BrC extracts collected during laboratory combustion of boreal peat and live spruce foliage. The atmospheric stability of BrC extracts varies with chromophore molecular size and fuel type: in particular, the high-molecular-weight fractions of both peat- and spruce-BrC are more resistant to photobleaching than their corresponding low-molecular-weight fractions, and total light absorption by peat-BrC persists over longer illumination timescales than that of spruce-BrC. Importantly, the BrC molecular size distribution itself varies with fuel properties (e.g., moisture content) and to an even greater extent with fuel type. Overall, our findings suggest that the accurate estimation of BrC radiative forcing, and the overall climate impact of wildfires, will require atmospheric models to consider the impact of regional diversity in vegetation/fuel types.