Quantum Computation of Hydrogen Bond Dynamics and Vibrational Spectra Journal Articles uri icon

  •  
  • Overview
  •  
  • Research
  •  
  • Identity
  •  
  • Additional Document Info
  •  
  • View All
  •  

abstract

  • Calculating observable properties of chemical systems is often classically intractable and widely viewed as a promising application of quantum information processing. Here, we introduce a new framework for solving generic quantum chemical dynamics problems using quantum logic. We experimentally demonstrate a proof-of-principle instance of our method using the QSCOUT ion-trap quantum computer, where we experimentally drive the ion-trap system to emulate the quantum wavepacket dynamics corresponding to the shared-proton within an anharmonic hydrogen bonded system. Following the experimental creation and propagation of the shared-proton wavepacket on the ion-trap, we extract measurement observables such as its time-dependent spatial projection and its characteristic vibrational frequencies to spectroscopic accuracy (3.3 cm-1 wavenumbers, corresponding to >99.9% fidelity). Our approach introduces a new paradigm for studying the chemical dynamics and vibrational spectra of molecules and opens the possibility to describe the behavior of complex molecular processes with unprecedented accuracy.

authors

  • Richerme, Philip
  • Revelle, Melissa C
  • Yale, Christopher G
  • Lobser, Daniel
  • Burch, Ashlyn D
  • Clark, Susan M
  • Saha, Debadrita
  • Lopez-Ruiz, Miguel Angel
  • Dwivedi, Anurag
  • Smith, Jeremy M
  • Norrell, Sam A
  • Sabry, Amr
  • Iyengar, Srinivasan S

publication date

  • August 17, 2023