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Effect of Carboxylic Acid Content on the Acute...
Journal article

Effect of Carboxylic Acid Content on the Acute Toxicity of Oil Sands Naphthenic Acids

Abstract

Fractions of methylated naphthenic acids (NAs) isolated from oil sands process-affected waterwere collected utilizing Kugelrohr distillation and analyzed by proton nuclear magnetic resonance (1H NMR) spectroscopy. 1H NMR analysis revealed that the ratio of methyl ester hydrogen atoms to remaining aliphatic hydrogen atoms increased from 0.130 to 0.214, from the lowest to the greatest molecular weight (MW) fractions, respectively, indicating that …

Authors

Frank RA; Fischer K; Kavanagh R; Burnison BK; Arsenault G; Headley JV; Peru KM; Van Der Kraak G; Solomon KR

Journal

Environmental Science and Technology, Vol. 43, No. 2, pp. 266–271

Publisher

American Chemical Society (ACS)

Publication Date

January 15, 2009

DOI

10.1021/es8021057

ISSN

0013-936X